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Which of the following is incorrect reg...

Which of the following is incorrect regarding concentrated nitric acid?

A

Sulphur is oxidised by conc. `HNO_(3)` to sulphuric acid

B

Carbon on treatment with conc. `HNO_(3)` yields `NO_(2)+CO_(2)+H_(2)O`

C

Phosphorus reacts with conc. `HNO_(3)` to yield orthophosphoric acid

D

Iodine is oxidized by conc. `HNO_(3)` to periodic acid

Text Solution

Verified by Experts

The correct Answer is:
4

Nitric acid is a powerful oxidizing agent.Teh concentrated acid behaves thsu with reducing agents:
`2HNO_(3)rarrH_(2)O+2NO_(2)+O`
`S+6HNO_(3)rarrH_(2)SO_(4)+2H_(2)O+6NO_(2)`
`C+4NHO_(3)rarrCO_(2)+2H_(2)O+4NO_(2)`
`P+5HNO_(3)rarrH_(3)PO_(4)+H_(2)O+5NO_(2)`
`I_(2)+10HNO_(3)rarr2HIO_(3)+4H_(2)O+10NO_(2)`
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Knowledge Check

  • Which of the following is incorrect regarding ozone?

    A
    it is oxidized `H_(2)S` to `SO_(2)`
    B
    it oxidized alkaline `KI` to potassium iodate or to potasium periodate depending upon the amount
    C
    its oxidizes dry iodine to `I_(4)O_(9)` a yellow power
    D
    silver metal is blackened by ozone.
  • Which of the following is incorrect regarding ozone?

    A
    At room temperature ozone is absorbed by turpentine oil and oil of cinnamon
    B
    Ozone truns an alchoholic solution of tetramethyl base violet
    C
    Ozone truns starch iodine paper blue ( in absence ofo ferrous sulphate) due to the liberation fo `I_(2)`.
    D
    Ozone adds to unsatured organic compounds at room temperature forming ozonic
  • Which of the following is incorrect regarding O_3

    A
    It is an allotrope of oxygen.
    B
    `d_(o-o)` is in between that of `O_2` and `H_2O_2`
    C
    It is an angular-shaped molecule.
    D
    It is paramagnetic like `O_2`
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