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Which of the following is the correct st...

Which of the following is the correct statement for `PH_(3)`?

A

It is extermely soluble in water

B

it is less basic then `NH_(3)`

C

It does not show reducing properties

D

it is nontoxic

Text Solution

Verified by Experts

The correct Answer is:
2

Phosphine is a very weak base. In fact ,the phosphonium ion `PH_(4)^(+)` ,the equivalent of the ammonium ion,is difficult to prepare.
`PH_(3)`, unlike `NH_(3)`, is not very soluble in water: aqueous solution are neutral. Relative to `NH_(3)`, it is very poisonous. Phosphine is a much more powerful reducing agent than ammonia,converting silver and copper (II) salts in solution to their phosphides which subsequently react to give the free metals:
`6Ag^(+)(aq)+PH_(3)(g)+3H_(2)(l)O rarr6Ag(s)+H_(3)PO_(3)(aq)+6H^(+)(aq.)`
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