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Phosphates can be estimated quantitative...

Phosphates can be estimated quantitatively by precipitating them as

A

`Ca_(3)(PO_(4))_(2)`

B

`AlPO_(4)`

C

`Mg_(3)(PO_(4))_(2)`

D

`MgNH_(4)PO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
4

Phosphates precipate magnesium ammonium phosphate when added to an ammoniacal solution of magnesium chloride .If this precipitate is washed, filtered and ignited it forms magnesium diphoshate .This can weighted and thus phosphates can be estimated qantitatively.
`2Mg^(2+)(NH_(4)^(+))PO_(4)^(3)(s)rarr(Mg^(2+))_(2)P_(2)O_(7)^(4-)(s)+2NH_(3)(g)+H_(2)O(l)`
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