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In the cyclo -S(8) molecule of rhombic s...

In the cyclo `-S_(8)` molecule of rhombic sulphur, all the `S-S` bond lengths and all the `S-S-S` bond angle are `"_____"` (approximate values ) respectively

A

`204`pm and `105^(@)`

B

`204`pm and `107^(@)`

C

`102`pm and `102^(@)`

D

`102`pm and `106^(@)`

Text Solution

Verified by Experts

The correct Answer is:
2

In all of the ring forms of `S`,the `S-S` distance is `204-2.6p m` and the bond angle `S-S-S` in the range `102-108^(@)`. They are all soluble in `CS_(2)`. Orthorhombic form of `S` is thermodynamically and most stable.
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