Home
Class 12
CHEMISTRY
The ions ClO^(-), ClO(2)^(-), ClO(3)^(-)...

The ions `ClO^(-), ClO_(2)^(-), ClO_(3)^(-)` and `ClO_(4)^(-)` are stabilized by strong

A

`ppi-ppi` bonding

B

`dpi-ppi` bonding

C

`ppi-dpi` bonding

D

`spi-ppi` bonding

Text Solution

Verified by Experts

The correct Answer is:
3

Chlorine forms a series of ocyacids and oxyanions for each of its positive odd oxidation states forms `+1,` to `+7`. The shpes fo the ions (and releated acids are based on a tetrahedral arrangment (`sp^(2)` hydridization ) around the `CI` atom.
The short chlorine -oxygen bonds in each of the ions indicate that multiple bonding must be present possibily involving some contribution to the `pi` bonding by the full `p` orbitals on the oxygen atoms and empty `d` orbials on the `CI` atoms .
Promotional Banner

Topper's Solved these Questions

  • THE P BLOCK ELEMENTS

    R SHARMA|Exercise Follow-up Test 19|9 Videos
  • THE P BLOCK ELEMENTS

    R SHARMA|Exercise Follow-up Test 20|11 Videos
  • THE P BLOCK ELEMENTS

    R SHARMA|Exercise Follow-up Test 17|10 Videos
  • THE D AND F BLOCK ELEMENTS

    R SHARMA|Exercise Archives|54 Videos

Similar Questions

Explore conceptually related problems

The correct order of o^(-) bond lengths in ClO^(-), ClO_(2)^(-), ClO_(3)^(-) and ClO_(4)^(-) is

Hybridisation of chlorine atom in ClO^(-), ClO_(2)^(-),ClO_(3)^(-) and ClO_(4)^(-) , respectively

Which of the following species, do not show disproportionation reaction and why ? ClO^(-) , ClO_(2)^(-) , ClO_(3)^(-) and ClO_(4)^(-) Also write reaction for each of the species that disproportionates.

The hybridization of Cl atom in ClO_(4)^(-) and ClO_(3)^(-) is

How many oxyanions among the following show disproportionation? ClO^(-), ClO_(2)^(-), ClO_(3)^(-), ClO_(4)^(-)

What is geometry of ClO_2^(ɵ),ClO_3^(ɵ) and ClO_4^(ɵ) ions?