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Among the following ,which one is the wr...

Among the following ,which one is the wrong statement

A

`PH_(5)` and `BiCl_(5)` do not exist

B

`ppi-ppi` bonds are present in `SO_(2)`

C

`SeF_(4)` and `CH_(4)` have same shape

D

`I_(3)^(+)` has bent geometery

Text Solution

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The correct Answer is:
3

`SeF_(4)implies` [steric number =`4`atoms+ `1` m lone pair]`implies`geometery is trigonal bipyramidal,shape is see -saw and `sp^(3) d` hybridization
`CH_(4)implies` [Steric number of `4` atoms+`0` lone pair]`implies`geometery as well as shape is trtrahedral an `sp^(3)` hybridization
(1) `H` is not sufficiently electronegative to contract `d`-orbitals and `Bi(+5)` is unstable due to incrt pair effect.
(2) In `SO_(2)` both `ppi-ppi` and `ppi-dpi` bonds are present
`I_(3)^(+) implies`[steric number=`2`atoms +`2` lone pairs ]`implies`geometery is tetrahedral shape is bent`//`angular and `sp^(3)` hybridization.
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