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Strong reducing behaviour of H(3)PO(4) i...

Strong reducing behaviour of `H_(3)PO_(4)` is due to :

A

High oxidation state of phosphorus

B

Presence of two`-OH` group and one `P-H` bond

C

Presence of one `-OH` group and two `P-H` bond

D

High electron gain enthalpy of phosphorus

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The correct Answer is:
To determine the strong reducing behavior of \( H_3PO_4 \) (phosphoric acid), we need to analyze the structure and bonding of the compound. However, it seems there is a correction needed in the question, as the strong reducing behavior is actually associated with \( H_3PO_2 \) (phosphorous acid), not \( H_3PO_4 \). ### Step-by-Step Solution: 1. **Identify the Correct Compound**: The question mentions \( H_3PO_4 \), but the strong reducing behavior is actually attributed to \( H_3PO_2 \). Therefore, we will focus on \( H_3PO_2 \). 2. **Analyze the Structure of \( H_3PO_2 \)**: - The structure of \( H_3PO_2 \) includes: - One phosphorus atom (P) - One double bond to an oxygen atom (O) - One hydroxyl group (–OH) - Two phosphorus-hydrogen (P–H) bonds - This can be represented as: \[ H_2P(=O)(–OH)(–H) \] 3. **Identify the Reducing Agents**: - The presence of P–H bonds in \( H_3PO_2 \) is crucial. The P–H bonds can donate electrons, which is a characteristic of reducing agents. - The P–H bonds can easily be oxidized, leading to the reduction of other species. 4. **Oxidation State of Phosphorus**: - In \( H_3PO_2 \), the oxidation state of phosphorus can be calculated as follows: - Let the oxidation state of phosphorus be \( x \). - The equation is: \[ 3(1) + x + 2(-2) = 0 \implies 3 + x - 4 = 0 \implies x = +1 \] - The oxidation state of phosphorus in \( H_3PO_2 \) is +1, which is relatively low compared to other phosphorus oxoacids. 5. **Conclusion**: - The strong reducing behavior of \( H_3PO_2 \) is due to the presence of P–H bonds, which can easily donate electrons, making it a strong reducing agent. ### Final Answer: The strong reducing behavior of \( H_3PO_2 \) is due to the presence of P–H bonds that can donate electrons.

To determine the strong reducing behavior of \( H_3PO_4 \) (phosphoric acid), we need to analyze the structure and bonding of the compound. However, it seems there is a correction needed in the question, as the strong reducing behavior is actually associated with \( H_3PO_2 \) (phosphorous acid), not \( H_3PO_4 \). ### Step-by-Step Solution: 1. **Identify the Correct Compound**: The question mentions \( H_3PO_4 \), but the strong reducing behavior is actually attributed to \( H_3PO_2 \). Therefore, we will focus on \( H_3PO_2 \). 2. **Analyze the Structure of \( H_3PO_2 \)**: ...
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