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In complexes off wea field ligands, Delt...

In complexes off wea field ligands, `Delta_(o) lt P` (pairing energy), the energy difference between `t_(2g) and e_(g)` sets is relatively less. Under the unfluence of strong field ligands, `Delta_(O) gt p` (Pairing energy), the energy difference between `t_(2g) and e_(g)` sets is relatively high.
Q. Which of the following is correct statement?

A

Complex `[Co(H_(2)O)_(6)]^(2+)` is more stable than `[Co(H_(2)O)_(6)]^(3+)`

B

All compounds of `Ni(II)` are bound to be outer-d-orbital complexes

C

Stability constant for `[Ni(en)_(3)]^(2+)` is greater than stability constant for `[Ni(NH_(3))_(6)]^(2+)`

D

`Delta_(oct)` for `[Cr(H_(2)O)_(6)]^(3+)` is greater than `Delta_(oct)` for `[Cr(NH_(3))_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C
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VK JAISWAL-CO-ORDINATION COMPOUNDS-LEVEL 3 (PASSAGE TYPE)
  1. An isomer of the complex Co(en)(2)(H(2)O)IC l(2), on reaction with con...

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  2. An isomer of the complex Co(en)(2)(H(2)O)IC l(2), on reaction with con...

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  3. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  4. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  5. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  6. Complex compounds are molecular compounds which retain their identitie...

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  7. Complex compounds are molecular compounds which retain their identitie...

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  8. Complex compounds are molecular compounds which retain their identitie...

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  9. Recent X-ray work, IR and other spectroscopic methods have proved that...

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  10. Recent X-ray work, IR and other spectroscopic methods have proved that...

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  11. On the basic of stability of complex ion in the solution, complexes ma...

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  12. On the basic of stability of complex ion in the solution, complexes ma...

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  13. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  14. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  15. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  16. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  17. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  18. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  19. Magnetic moment, ionic conductance and colligative properties are usef...

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  20. Magnetic moment, ionic conductance and colligative properties are usef...

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