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STATEMENT-1: Tetrahedral complexes with ...

STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optical isomerism .
and
STATEMENT-2: They lack plane of symmetry .

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

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The correct Answer is:
C
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Which of the folloiwng complexes in not expected to exhibit optical isomerism? .

The complex which exhibits geometrical as well as optical isomerism is :

Which of the following complexes exhibit optical isomerism?

STATEMENT-1: Tetrahedral complexes are always high spin complexes . STATEMENT-2: Crystal field splitting energy in tetrahedral complexes is 2/3 of the Delta_(0) (crystal field splitting energy in octahedral complexes). STATEMENT-3: Tetrahedral complex [MABCD]^(pm n) is optically active .

Which of the following complex species is not expected to exhibit optical isomerism ?

Consider the following satements : S_(1): Generally square planare complexes show geometrical isomerism but do not exhibit optical isomerism because thy do not possess plane of symmetry . S_(2): Delta_(t)=(4)/(9)Delta_(0) S_(3) : In octahedral complexes each electron entering teh t_(2g) orbitals stabilizes the complex ion by 0.4 Delta_(0) and each electron entering teh e_(g) orbital destabilizes the complex by an amount of 0.6 Delta_(0) Select the correct statement from the codes given below.

VK JAISWAL-CO-ORDINATION COMPOUNDS-ASSERTION-REASON TYPE QUESTIONS
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  2. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  3. STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optic...

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  4. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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  5. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

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  6. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

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  7. Assertion: Transition metal ion forming octahedral complexes undergo s...

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  8. Assertion: Complex ion [Co(NH(3))(6)]^(2+) is readily oxidized to [Co(...

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  9. Assertion: Hydrazine is a neutral ligand. Reason: It has two N as do...

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  10. Reason: Complex anion [Re(2)Cl(8)]^(2-) has one delta-bond, one sigma ...

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  11. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  12. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  13. Assertion: [Ti(H(2)O)(6)]^(4+) is coloured while [Sc(H(2)O)(6)]^(3+) i...

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  14. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  15. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  16. Assertion: Tetrahedral complexes with chiral structure exhibit optical...

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  17. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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  18. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

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  19. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

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  20. Assertion: Transition metal ion forming octahedral complexes undergo s...

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