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Strong yellow colour of Ce^(4+) solution...

Strong yellow colour of `Ce^(4+)` solutions and blood red colour of `Sm^(2+)` solution arises due to :

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"When NH_(4)SCN (colourless) is added to dilute solution of FeCl_(3) (light yellow), the colour o the solution becomes deep red but on addition of NH_(4)Cl solution (colourless) the red colour faded." Why?