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XO+I(2)O(5)(s) to CO(2)+I(2)...

`XO+I_(2)O_(5)(s) to CO_(2)+I_(2)`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

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The correct Answer is:
c
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A mixture of CO and CO_(2) when treated with I_(2)O_(5) gives I_(2) vapours accoeding to the following equation: 5CO+I_(2)O_(5)to5CO_(2)+I_(2) I_(2) vapour was separated and treated with HClO_(4) and the resultant HIO_(4) required 0.001 " mol of "hlycerol for complete oxidation. After treatment with I_(2)O_(5) and removal of I_(2) ,t he mixture was treated with excess of 0.1 N NaOH solution and finally this solution required 20 " mL of " 1 N HCl to reach end point using phenolphthalein as indicator, followed by methyl orange as indicator after the first end point, 10 " mL of " further HCl was consumed. Q. The total volume of NaOH used in the problem is

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The percentage of oxygen in an organic compound can be determined by converting O of the compound quantitatively into (i) CO_(2) (ii) I_(2)O_(5) (iii) I_(2) (iv) CO

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