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In alcohols , the -OH group is attache...

In _________ alcohols , the -OH group is attached to a `sp^2` hybridised carbon atom.

A

allylic

B

benzylic

C

vinylic

D

all of these

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The correct Answer is:
To solve the question, "In _________ alcohols, the -OH group is attached to a `sp^2` hybridised carbon atom," we need to identify the type of alcohol where the hydroxyl (-OH) group is bonded to a carbon atom that is `sp^2` hybridized. ### Step-by-Step Solution: 1. **Understanding Hybridization**: - The hybridization of a carbon atom can be determined by its steric number, which is the sum of the number of sigma bonds and lone pairs around the carbon atom. - For `sp^2` hybridization, the steric number is 3. This means the carbon atom is bonded to three other atoms (which can include other carbons or hydrogens) and has no lone pairs. 2. **Identifying Alcohol Types**: - We need to consider different types of alcohols and their structures to see which one has the -OH group attached to an `sp^2` hybridized carbon. 3. **Types of Alcohols**: - **Allylic Alcohol**: The -OH group is attached to a carbon that is adjacent to a carbon-carbon double bond. The carbon with the -OH group is `sp^2` hybridized. - **Benzylic Alcohol**: The -OH group is attached to a carbon that is adjacent to a benzene ring. The carbon with the -OH group is also `sp^2` hybridized. - **Vinylic Alcohol**: The -OH group is attached to a carbon that is part of a double bond. The carbon with the -OH group is `sp^2` hybridized. 4. **Conclusion**: - Among the options, both allylic and benzylic alcohols have the -OH group attached to an `sp^2` hybridized carbon atom. However, the question specifically asks for one type of alcohol. - The correct answer is **benzylic alcohol**, as it is a common example where the -OH group is attached to a carbon adjacent to a benzene ring, which is `sp^2` hybridized. ### Final Answer: In **benzylic** alcohols, the -OH group is attached to a `sp^2` hybridised carbon atom. ---
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Assertion: Aryl halides are highly reactive towards nucleophilic substitution reactions. Reason: In case of halorenes, halogen atom is attached to sp hybridised carbon atom.

TARGET PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS -CRITICAL THINKING
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  2. Monohydric alcohols are functional isomers of .

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  3. In alcohols , the -OH group is attached to a sp^2 hybridised carbon...

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  4. The structural formula of cyclohexanol is .

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  5. IUPAC name of neopentyl alcohol is .

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  6. The molecular formula of sorbitol is.

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  7. Ethylene glycol is prepared by the hydrolysis of .

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  8. To crazy out the conversion of unsaturated aldehyde to unsaturated alc...

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  9. Which of the following reactions does NOT lead to formation of ethanol...

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  10. Which of the following can give monohydric alcohols ?

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  11. The product 'C' in the following reaction is . CH3Br overset( dil . ...

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  12. C(2)H(5)MgI reacts with HCHO to form last product :

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  13. CH3-overset(CH3)overset(|)C=O underset((ii)H2O)overset((i)CH3MgI)to X ...

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  14. A tertiary alcohol is obtained when Grignard reagent react with

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  15. The R-O-H bong angle in case of methanol is

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  16. Least soluble alcohol in water is .

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  17. Decreasing order of boiling points of n-Petanol (A), n-Pentane (B), Pe...

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  18. Boiling point of C2H5OH is higher as compared to C2H5SH on account of ...

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  19. The organic acids are weakly acidic while alcohols are neutral even th...

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