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Three alcohols (i) CH3CH2CH2OH, (ii)...

Three alcohols
(i) `CH_3CH_2CH_2OH,`
(ii) `CH_3-CHOH-CH_3and`
(iii) `CH_3-C(CH_3)(OH)-CH_3`
were treated seperately with Lucas reagent (Conc. `HCl+ZnCl_2`) . What results do you expect at room temperature.

A

(ii) and (iii) react immediately and (i) in about 5 minutes .

B

(iii) reacts immediately , (ii) reacts in about 5 minutes and (i) not at all.

C

(i) reacts immediately , (ii) reacts in about 5 minutes and (iii) not at all.

D

(i) reacts in about 5 minutes , (ii) reacts in about 15 minutes and (iii) not at all.

Text Solution

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The correct Answer is:
B
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Alcohols (i) CH_(3)CH_(2)CH_(2)OH (ii) CH_(3)-CHOH-CH_(3) and (iii) CH_(3)-C(CH_(3))(OH)-CH_(3) were treated with Kucas reagent (Conc. HCI+ZnCI_(2)) . What results do you expect at room temperature?

CH_3-CH_2-CH_2-CH_2-OH and CH_3-C(CH_3)_2-OH are

IUPAC name is CH_3-CH(OH)-CH_2-CH_3 CH_3-CH_2-O-CH_2-CH_3

IUPAC name is CH_3-CH_2-CH(OH)-CH(CH_3)-CH_3

Write the IUPAC name of CH_3-CH_2-CH_2-CH_2-CH(OH)-CH(OH)-CH_3

Write the IUPAC name of CH_3-CH_2-C(CH_3)(OH)-CH_3

Convert CH_(3)OH into CH_(3)CH_(2)OH, CH_(3)CH(OH)CH_(3) and (CH_(3))_(3)COH . Only one type of reagent is permitted in each step.

Write the IUPAC name of CH_3-CH_2-C(OH)(CH_2-CH_2-CH_3)-CH_2-CH_3

Write the IUPAC name of CH_3-CH_2-CH(OH)-CH_2-CH_2-CH(CH_3)-CH_2-CH_3

TARGET PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS -EVALUATION TEST
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  4. In the formation of tertiary alcohol from C2H5MgBr and acetone , which...

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  5. Which of the following has highest solubility in water ?

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  6. Three alcohols (i) CH3CH2CH2OH, (ii) CH3-CHOH-CH3and (iii) CH3-C...

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  7. R-OH +SOCl2 overset("Pyridine") to R-Cl+SO2+HCl Pyridine in the abov...

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  8. Which alcohol is difficult to oxidize ?

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  9. Which one of the following alcohols undergoes acid-catalysed dehydrat...

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  10. Which of the following alcohols gives the best yield to dialkyl ether...

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  11. Phenoxide ion is more stable than phenol due to the .

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  12. Attacking species in bromination of phenol is .

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  13. Oxidation of by chromic acid yields benzoquinone.

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  14. Four organic compound have functional group as shown below : A:-unders...

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  15. The conversion of m-nitrophenol to resorcinol inivolves respectively:

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  16. The correct order of acid strength of the following substituted pheno...

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  17. In the presence of alumina as catalyst , two alcohol molecules will u...

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  18. An ether is obtained when phenol reacts with .

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  19. Methoxymethane is obtained from .

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  20. Which reagent is used to get only iodoethane from diethyl ether ?

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