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Consider the acidity of the carboxylic a...

Consider the acidity of the carboxylic acids:
(1) `PhCOOH`
(2) `o-NO_(2) C_(6) H_(4) COOH`
(3) `p-NO_(2) C_(6) H_(4) COOH`
(4) `m-NO_(2) C_(6) H_(4) COOH`
Which of the following order is correct?

A

`ii gt iv gt igt iii`

B

`ii gt iv gt iii gt i`

C

`igtii gt iii gt iv`

D

`ii gt iii gt iv gti`

Text Solution

Verified by Experts

The correct Answer is:
D
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Consider the methyl substituted benzoic acids. 1. PhCOOH 2. o-CH_(3)C_(6)H_(4)COOH 3. p - CH_(3)C_(6)H_(4)COOH 4. m-CH_(3)C_(6)H_(4)COOH The correct sequence of acidity is

TARGET PUBLICATION-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-COMPETITIVE THINKING
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