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CHEMISTRY
Amines behave as:...

Amines behave as:

A

Lewis acids

B

Lewis bases

C

Aprotic acids

D

Amphoteric compounds

Text Solution

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The correct Answer is:
B
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In which of the following reactions does the amine behaves as an acid ?

Amines are basic compounds They act as Lewis base due to the presence of lone pair electrons at nitrogen Amines also behave as base as well as Bronsted inductive effect, steric hindrance and resosnance. CH_(3)-NH_(2)+HOH hArr CH_(3)-NH_(3)^(+)+OH^(-) CH_(3)-NH_(2)+H^(+)Cl^(-)hArr CH_(3)-NH_(3)^(+)+Cl^(-) Alkyl groups and electron groups hence these groups increases the electron density at nitrogen as well as the basic amines character of amines. Basic character of teritary amines is reduced due to the steric hindrance of three alkyl groups. Experimentally it is observed that stronger bases have smaller values of pK_(b) greater value of K_(b) . Which among the following is the most basic in aqueous medium?

Amines are basic compounds They act as Lewis base due to the presence of lone pair electrons at nitrogen Amines aho behave as base as well as Bronsted inductive effect, steric hindrance and resosnance. CH_(3)-NH_(2)+HOH hArr CH_(3)-NH_(3)^(+)+OH^(-) CH_(3)-NH_(2)+H^(+)Cl^(-)hArr CH_(3)-NH_(3)^(+)+Cl^(-) Alkyl groups and electron groups hence these groups increases the electron density at nitrogen as well as the basic amines character of amines. Basic character of teritary amines is reduced due to the steric hindrance of three alkyl groups. Experimentally it is observed that stronger bases have smaller values of pK_(b) greater value of K_(b) . Which among hte following is the most basic in aqueous medium?

Amines are basic compounds They act as Lewis base due to the presence of lone pair electrons at nitrogen Amines aho behave as base as well as Bronsted inductive effect, steric hindrance and resosnance. CH_(3)-NH_(2)+HOH hArr CH_(3)-NH_(3)^(+)+OH^(-) CH_(3)-NH_(2)+H^(+)Cl^(-)hArr CH_(3)-NH_(3)^(+)+Cl^(-) Alkyl groups and electron groups hence these groups increases the electron density at nitrogen as well as the basic amines character of amines. Basic character of teritary amines is reduced due to the steric hindrance of three alkyl groups. Experimentally it is observed that stronger bases have smaller values of pK_(b) greater value of K_(b) . Which of the following is the most basic?

TARGET PUBLICATION-COMPOUND CONTAINING NITROGEN -COMPETITIVE THINKING
  1. Which of the following statement(s) is/are incorrect in case of Hofm...

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  2. Indicate which nitrogen compound amongst the following would undergo H...

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  3. Amines behave as:

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  4. The correct statement regarding the basicity of arylamines is .

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  5. In case of substituted aniline the group which decreases the basic...

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  6. Select the compound which on treatment with nitrous acid liberates nit...

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  7. Diethyl amine when treated with nitrous acid yields

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  8. The amine 'A' when treated with nitrous acid gives yellow oily substan...

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  9. When amine reacts with nitrous acid, the primary, secondary and tertia...

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  10. During acetylation of amines

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  11. Which one of the following compounds when heated with KOH and a primar...

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  12. Which one of the following will give carbylamine test ?

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  13. The reaction of aniline with chloroform under alkaline conditions lead...

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  14. Which of the following reaction does NOT occur ?

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  15. An organic compound X having molecular formula C4H11N reacts with p-to...

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  16. Identify the product 'C' in the folowing reaction. "Aniline"underset...

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  17. Nitration of aniline also gives m-nitro anilime, in stron acidic mediu...

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  18. When aniline is treated will sodium nitrite and hydrochloric acid at 0...

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  19. In Gattermann reaction , a diazonium group is replaced by ulX using u...

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  20. Which of the following is NOT formed by Sandmeyer reaction ?

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