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The standard reduction potentials at 25^...

The standard reduction potentials at `25^(@)C` for the following half reactions are given against each:
`Zn^(2+) (a.q) + 2e^(-) hArr Zn (s) : " " - 0.762`
`Cr^(3+) (a.q) 3e^(-) hArr Cr (s) , " " - 0.740`
`2H^(+) + 2e^(-) hArr H_(2) (g), " " 0.00`
`Fe^(3+) + e^(-) hArr Fe^(2+) , " " 0.77`
Which is the strongest reducing agent?

A

`Zn_((s))`

B

`Cr_((s))`

C

`H_(2(g))`

D

`Fe_((aq))^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
A

More negative the value of reduction potential , stronger is the reducing property i.e. power to accept electrons.
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At 298 K, the standard reduction potentials for the following half reactions are given. Which acts as anode with others in electrochemical cell Zn^(+2)(aq) + 2e^(-) to Zn(s), -0.762 Cr^(+3)(aq) + 3e^(-) to Cr(s), -0.740 2H^(+)(aq) + 2e^(-) to H_2(g), -0.000 Fe^(+3)(aq) + e^(-) to Fe^(2+)(aq) , +0.762

The standard reduction potentials at 298K for the following half cells are given : ZN^(2+)(aq)+ 2e^(-)Zn(s) , E^(@) = - 0.762V Cr^(3+)(aq)+ 3e^(-) Cr(s) , E^(@) = - 0.740V 2H^(+) (aq)+2e^(-) H_(2)(g) , E^(@)= 0.000V Fe^(3+)(aq)+ e^(-) Fe^(2+)(aq) , E^(@) = 0.770V which is the strongest reducing agent ?

The standard reduction potentials at 298K, for the following half cells are given: Zn^(2+)(aq)+2e^(-)hArrZn(s):E^(@)=-0.762V Cr^(3+)(aq)+3e^(-)hArrCr(s):E^(@)=-0.740V 2H^(+)(aq)+2e^(-)hArrH_(2)(g), E^(@)=0.000V Fe^(3+)(aq)+e^(-)hArrFe^(2+)(aq),E^(@)=0.770V Which is the stronget reducing agent?

The standard potentials at 298 K for the following halfreactions are as given Zn^(2+) + 2e underset(larr)(rarr) Zn E^o =- 0/ 762 V . 2 H^+ + 2 Erarr H_2 (g) E^o = 0.000 V Cr^(3+) + 3e underset(larr)(rarr) Cr E^o =- 0.740 V Fe^(3+) 2e rarr Fe^(2+) E^o =0.772 V Which of the following is the strongest reducing agent ?

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