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A metal M reacts with N(2) to give a com...

A metal `M` reacts with `N_(2)` to give a compound `'A'(M_(3)N)`. 'A' on heating at high temperature gives back `'M'` and `'A'` on reacting with `H_(2)O` gives a gas 'B'.'B' turns `CuSO_(4)` solution blue on passing through it `A` and `B` can be

A

Al and `NH_(3)`

B

Li and `NH_(3)`

C

Na and `NH_(3)`

D

Mg and `NH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

Lithium form nitride on heating with nitrogen. Lithium nitride gives ammonia when heated with `H_(2)O`. Ammonia gas form tetrammine copper complex with `CuSO_(4)` solution.
`6Li +N_(2) to 2Li_(3)N`
`Li_(3)N +3H_(2)O to 3LiOH +NH_(3)`
`CuSO_(4) +4NH_(3) to [Cu(NH_(3))_(4) ] SO_(4)`
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