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Among the following oxoacids, the correc...

Among the following oxoacids, the correct decreasing order of acid strength is:

A

`HOCl gt HClO_(2) gt HClO_(3) gt HClO_(4)`

B

`HClO_(4) gt HOCl gt HClO_(2) gt HClO_(3)`

C

`HClO_(4) gt HClO_(3) gt HClO_(2) gt HOCl`

D

`HClO_(2) gt HClO_(4) gt HClO_(3) gt HOCl`

Text Solution

Verified by Experts

The correct Answer is:
C

Decreasing order of strength of oxoacids.
`HClO_(4) gt HClO_(3) gt HClO_(2) gt HOCl`
Considered the structure of conjugate bases.

Negative charge is more delocalized on `ClO_(4)^(-)` due to resonance , hence `ClO_(4)^(-)` is more stable (and less basic)
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