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Statement 1: D-Cl bond is stronger than ...

Statement 1: D-Cl bond is stronger than H-Cl bond.
statement 2: Chlorine reacts more rapidly with `H_(2)` than with `D_(2)`.

A

Statement 1 is true, statement 2 is true, statement 2 si a correct explanation for statement 15

B

Statement 1 is true, statement 2 is true, statement 2 is not a correct explanation for statement 15

C

Statement 1 is true, statement 2 is false

D

Statement 1 is false, statement 2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding the bond strength of D-Cl versus H-Cl and the reactivity of chlorine with H2 versus D2, we can break down the reasoning step by step. ### Step 1: Understanding Bond Strength - **Bond Strength Comparison**: The bond strength between two atoms can be influenced by the masses of the atoms involved. In this case, we are comparing the D-Cl bond with the H-Cl bond. - **Isotopes**: Deuterium (D) is an isotope of hydrogen (H) with one neutron, making it heavier than hydrogen. The heavier the atom in a bond, the stronger the bond tends to be due to reduced vibrational amplitude. ### Step 2: Analyzing Statement 1 - **Statement 1**: "D-Cl bond is stronger than H-Cl bond." - **Conclusion**: This statement is generally considered **true** because the D-Cl bond is stronger than the H-Cl bond due to the reduced vibrational amplitude of the heavier deuterium atom. ### Step 3: Understanding Reactivity - **Reactivity Comparison**: The reactivity of a molecule often depends on the bond strength. Weaker bonds tend to break more easily, leading to higher reactivity. - **Chlorine Reaction**: Chlorine reacts with hydrogen (H2) and deuterium (D2). Since H-Cl bonds are weaker than D-Cl bonds, H2 will react more readily with chlorine than D2. ### Step 4: Analyzing Statement 2 - **Statement 2**: "Chlorine reacts more rapidly with H2 than with D2." - **Conclusion**: This statement is also **true** because the H-Cl bond is weaker than the D-Cl bond, making H2 more reactive with chlorine. ### Final Conclusion - Both statements are true: - Statement 1 is true: D-Cl bond is stronger than H-Cl bond. - Statement 2 is true: Chlorine reacts more rapidly with H2 than with D2.

To analyze the given statements regarding the bond strength of D-Cl versus H-Cl and the reactivity of chlorine with H2 versus D2, we can break down the reasoning step by step. ### Step 1: Understanding Bond Strength - **Bond Strength Comparison**: The bond strength between two atoms can be influenced by the masses of the atoms involved. In this case, we are comparing the D-Cl bond with the H-Cl bond. - **Isotopes**: Deuterium (D) is an isotope of hydrogen (H) with one neutron, making it heavier than hydrogen. The heavier the atom in a bond, the stronger the bond tends to be due to reduced vibrational amplitude. ### Step 2: Analyzing Statement 1 - **Statement 1**: "D-Cl bond is stronger than H-Cl bond." ...
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