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A' on heating at 700^(@)C in air gives a...

A' on heating at `700^(@)C` in air gives a white infusible amorphous powder (B) which is decomposed when heated in the currect of steam to give white powder 'C' and a gas 'D'.'D' turns red litmus blue and in aqueous solution , gives reddish brown ppt with `K_(2)HgI_(4)`. compound 'C on strong heating gives 'E.
'A' is

A

B

B

Si

C

`P_(4)`

D

`N_(2)`

Text Solution

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The correct Answer is:
To solve the problem step by step, we need to analyze the information provided and deduce the compounds involved in the reactions. ### Step 1: Identify Compound A The question states that compound A, when heated at 700°C in air, produces a white infusible amorphous powder (B). Given that the process involves heating in air, we can deduce that compound A is likely a metal or metalloid that reacts with oxygen to form an oxide. **Hint:** Think about elements that can form oxides and are stable at high temperatures. ### Step 2: Determine Compound B The white infusible amorphous powder (B) formed from A is likely a metal oxide. Based on the context, we can consider that A is boron (B). When boron is heated in air, it forms boron oxide (B2O3), which is a white infusible powder. **Hint:** Consider the properties of boron and its oxides. ### Step 3: Analyze the Reaction with Steam When compound B (B2O3) is heated in the current of steam, it decomposes to form a white powder (C) and a gas (D). The reaction can be represented as: \[ \text{B2O3} + 3 \text{H2O} \rightarrow 2 \text{H3BO3} + \text{NH3} \] Here, H3BO3 (boric acid) is the white powder (C), and ammonia (NH3) is the gas (D). **Hint:** Remember that steam (water vapor) can react with certain oxides to form acids. ### Step 4: Identify Gas D The gas D produced is ammonia (NH3), which is known to turn red litmus blue, indicating its basic nature. **Hint:** Think about the properties of ammonia and its behavior in aqueous solutions. ### Step 5: Analyze the Reaction of Compound C When compound C (H3BO3) is heated strongly, it decomposes to form compound E. The reaction can be represented as: \[ 2 \text{H3BO3} \rightarrow \text{B2O3} + 3 \text{H2O} \] Compound E is thus B2O3 (boron trioxide). **Hint:** Consider the thermal stability of boric acid and what it decomposes into upon heating. ### Final Answer Based on the deductions made, we conclude that: - A is **Boron (B)**. - B is **Boron oxide (B2O3)**. - C is **Boric acid (H3BO3)**. - D is **Ammonia (NH3)**. - E is **Boron trioxide (B2O3)**. ### Summary - **A**: Boron (B) - **B**: Boron oxide (B2O3) - **C**: Boric acid (H3BO3) - **D**: Ammonia (NH3) - **E**: Boron trioxide (B2O3)

To solve the problem step by step, we need to analyze the information provided and deduce the compounds involved in the reactions. ### Step 1: Identify Compound A The question states that compound A, when heated at 700°C in air, produces a white infusible amorphous powder (B). Given that the process involves heating in air, we can deduce that compound A is likely a metal or metalloid that reacts with oxygen to form an oxide. **Hint:** Think about elements that can form oxides and are stable at high temperatures. ### Step 2: Determine Compound B ...
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