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A' on heating at 700^(@)C in air gives a...

A' on heating at `700^(@)C` in air gives a white infusible amorphous powder (B) which is decomposed when heated in the currect of steam to give white powder 'C' and a gas 'D'.'D' turns red litmus blue and in aqueous solution , gives reddish brown ppt with `K_(2)HgI_(4)`. compound 'C on strong heating gives 'E.
'C' is

A

`B_(2)O_(3)`

B

`H_(3)BO_(3)`

C

`P_(2)O_(5)`

D

`SiO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the information provided and deduce the compounds involved. ### Step 1: Identify Compound A The problem states that compound A, when heated at 700°C in air, produces a white infusible amorphous powder B. Since the reaction occurs in air, which consists mainly of nitrogen and oxygen, we can deduce that compound A is likely a boron compound, specifically boron nitride (BN). **Hint:** Consider common compounds that can react with air at high temperatures to form stable oxides or nitrides. ### Step 2: Identify Compound B When boron nitride (BN) is heated in air, it forms boron oxide (B2O3) as compound B. B2O3 is a white, amorphous powder that is infusible. **Hint:** Look for the products of boron compounds when they react with oxygen at high temperatures. ### Step 3: Heating Compound B with Steam Next, compound B (B2O3) is heated in the presence of steam (H2O). This reaction leads to the formation of compound C and gas D. The reaction of boron oxide with water typically produces boric acid (H3BO3) and hydrogen gas (H2). **Hint:** Consider the reactions of metal oxides with water and how they can form acids or bases. ### Step 4: Identify Compound C From the previous step, we deduce that compound C is boric acid (H3BO3). **Hint:** Think about the products formed when oxides of non-metals react with water. ### Step 5: Identify Gas D Gas D is produced alongside compound C. The problem states that gas D turns red litmus blue, indicating it is basic in nature. Since hydrogen gas (H2) does not turn litmus blue, we can conclude that gas D is ammonia (NH3), which is produced when boric acid reacts with a base. **Hint:** Look for gases that are basic and can affect litmus paper. ### Step 6: Reaction of Compound C to Form Compound E When boric acid (H3BO3) is heated strongly, it can dehydrate to form boron trioxide (B2O3), which is compound E. **Hint:** Consider the thermal decomposition of acids and how they can yield oxides. ### Final Answer Thus, compound C is **H3BO3 (boric acid)**.

To solve the problem step by step, we will analyze the information provided and deduce the compounds involved. ### Step 1: Identify Compound A The problem states that compound A, when heated at 700°C in air, produces a white infusible amorphous powder B. Since the reaction occurs in air, which consists mainly of nitrogen and oxygen, we can deduce that compound A is likely a boron compound, specifically boron nitride (BN). **Hint:** Consider common compounds that can react with air at high temperatures to form stable oxides or nitrides. ### Step 2: Identify Compound B ...
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