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A' on heating at 700^(@)C in air gives a...

A' on heating at `700^(@)C` in air gives a white infusible amorphous powder (B) which is decomposed when heated in the currect of steam to give white powder 'C' and a gas 'D'.'D' turns red litmus blue and in aqueous solution , gives reddish brown ppt with `K_(2)HgI_(4)`. compound 'C on strong heating gives 'E.
'B' is

A

`BN`

B

`B_(2)O_(3)`

C

`SiO_(2)`

D

`P_(4)O_(10)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the information given in the question and deduce the compounds involved. ### Step 1: Identify Compound A The question states that compound A, when heated in air at 700°C, produces a white infusible amorphous powder B. The most likely candidate for compound A is **Boron (B)**, as it reacts with oxygen in the air to form boron oxide. **Hint:** Consider elements that can react with oxygen to form oxides at high temperatures. ### Step 2: Determine Compound B When boron (A) is heated in air, it forms **Boron Trioxide (B2O3)**, which is a white infusible amorphous powder. Therefore, compound B is **Boron Trioxide (B2O3)**. **Hint:** Think about the oxides formed by elements when they react with oxygen. ### Step 3: Reaction of Compound B with Steam Next, compound B (B2O3) is heated in the presence of steam (water vapor). The reaction of boron trioxide with steam produces **Boric Acid (H3BO3)**, which is a white powder (C), and a gas (D). **Hint:** Consider how oxides react with water to form acids or bases. ### Step 4: Identify Compound C The white powder C formed in this reaction is **Boric Acid (H3BO3)**. **Hint:** Recall the common acids formed from oxides when they react with water. ### Step 5: Identify Gas D The gas D produced in this reaction is **Ammonia (NH3)**. The question states that D turns red litmus blue, indicating that it is basic in nature. Ammonia is a well-known basic gas. **Hint:** Think about gases that are basic and can turn litmus paper blue. ### Step 6: Reaction of Compound C When boric acid (C) is strongly heated, it decomposes to form **Boron Oxide (B2O3)** again, which is compound E. **Hint:** Consider the thermal stability of acids and their decomposition products when heated. ### Conclusion Based on the deductions made through the steps: - **Compound A** is **Boron (B)**. - **Compound B** is **Boron Trioxide (B2O3)**. - **Compound C** is **Boric Acid (H3BO3)**. - **Gas D** is **Ammonia (NH3)**. - **Compound E** is **Boron Oxide (B2O3)**. Thus, the final answer is that **B is Boron Trioxide (B2O3)**.

To solve the problem step by step, we will analyze the information given in the question and deduce the compounds involved. ### Step 1: Identify Compound A The question states that compound A, when heated in air at 700°C, produces a white infusible amorphous powder B. The most likely candidate for compound A is **Boron (B)**, as it reacts with oxygen in the air to form boron oxide. **Hint:** Consider elements that can react with oxygen to form oxides at high temperatures. ### Step 2: Determine Compound B ...
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