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While writing the formula of ferrous oxi...

While writing the formula of ferrous oxide it is written as `(FeO)`, because it is

A

Non-stoichiometric

B

Non-existant

C

Paramagnetic

D

Ferromagnetic

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The correct Answer is:
To understand why the formula for ferrous oxide is written as FeO, we need to analyze the oxidation states of iron in this compound and the concept of non-stoichiometry. ### Step-by-Step Solution: 1. **Identify the Oxidation State of Iron in Ferrous Oxide:** - In ferrous oxide (FeO), iron (Fe) has an oxidation state of +2. This is because oxygen (O) typically has an oxidation state of -2. To balance the charges in the compound, iron must be +2. 2. **Understanding the Formula:** - The formula FeO indicates that there is one iron atom (Fe) with a +2 charge and one oxygen atom (O) with a -2 charge. This results in a neutral compound overall. 3. **Comparison with Ferric Oxide:** - In contrast, ferric oxide (Fe2O3) contains iron in the +3 oxidation state. Here, two iron atoms contribute a total of +6, which is balanced by three oxygen atoms contributing a total of -6. 4. **Concept of Non-Stoichiometry:** - Non-stoichiometric compounds are those that do not have a fixed ratio of their constituent elements. In the case of ferrous oxide, it can exhibit non-stoichiometric behavior, meaning that the ratio of iron to oxygen can vary slightly under certain conditions. 5. **Conclusion:** - Therefore, the formula FeO for ferrous oxide is derived from the +2 oxidation state of iron and the -2 oxidation state of oxygen. The correct answer to the question is that it is due to "non-stoichiometry." ### Final Answer: The formula for ferrous oxide is written as FeO because it exhibits non-stoichiometric behavior.
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