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Which of the following is coloured...

Which of the following is coloured

A

`ScCl_(3)`

B

`TiO_(2)`

C

`MnSO_(4)`

D

`ZnSO_(4)`

Text Solution

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The correct Answer is:
To determine which of the given compounds is colored, we need to analyze the oxidation states and electronic configurations of the elements involved, particularly focusing on the presence of unpaired electrons in their d-orbitals. Compounds with unpaired electrons typically exhibit color due to d-d transitions. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds given are SCCl3, TiO2, MnSO4, and ZnSO4. 2. **Analyze SCCl3**: - **Element**: Scandium (Sc) - **Oxidation State**: +3 - **Electronic Configuration**: Sc (atomic number 21) has the configuration 4s² 3d¹. - **For Sc +3**: The configuration becomes 4s⁰ 3d⁰. - **Unpaired Electrons**: There are no unpaired electrons (0 unpaired). - **Color**: Colorless. 3. **Analyze TiO2**: - **Element**: Titanium (Ti) - **Oxidation State**: +4 - **Electronic Configuration**: Ti (atomic number 22) has the configuration 4s² 3d². - **For Ti +4**: The configuration becomes 4s⁰ 3d⁰. - **Unpaired Electrons**: There are no unpaired electrons (0 unpaired). - **Color**: Colorless. 4. **Analyze MnSO4**: - **Element**: Manganese (Mn) - **Oxidation State**: +2 - **Electronic Configuration**: Mn (atomic number 25) has the configuration 4s² 3d⁵. - **For Mn +2**: The configuration becomes 4s⁰ 3d⁵. - **Unpaired Electrons**: There are 5 unpaired electrons (5 unpaired). - **Color**: Colored (due to unpaired electrons). 5. **Analyze ZnSO4**: - **Element**: Zinc (Zn) - **Oxidation State**: +2 - **Electronic Configuration**: Zn (atomic number 30) has the configuration 4s² 3d¹⁰. - **For Zn +2**: The configuration becomes 4s⁰ 3d¹⁰. - **Unpaired Electrons**: There are no unpaired electrons (0 unpaired). - **Color**: Colorless. 6. **Conclusion**: Among the compounds analyzed, only MnSO4 has unpaired electrons and is therefore colored. ### Final Answer: The colored compound is **MnSO4**.

To determine which of the given compounds is colored, we need to analyze the oxidation states and electronic configurations of the elements involved, particularly focusing on the presence of unpaired electrons in their d-orbitals. Compounds with unpaired electrons typically exhibit color due to d-d transitions. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds given are SCCl3, TiO2, MnSO4, and ZnSO4. 2. **Analyze SCCl3**: - **Element**: Scandium (Sc) ...
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ERRORLESS -D & P-BLOCK ELEMENTS-Ordinary Thinking (Compounds of d & f block elements)
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  5. In the extraction of copper when molten copper is cooled slowly, blist...

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  6. The most impure form of iron is

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  7. Parke's process of desilverization of lead depends upon

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  8. Match the item under List I with the compounds/elements from the List ...

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  9. Spiegeleisen is an alloy of

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  10. The presence of Si in steel gives it

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  11. The presence of Mn in steel produces

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  12. The addition of metal like Cr, Mn W and Ni to ordinary steel makes it

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  13. Stainless steel is non-corrosive. This character is more prominent in

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  14. When little vanadium is mixed with steel, it becomes

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  15. To obtain steel entirely free from sulphur and phosphorus, the process...

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  16. A clock spring is heated to redness and then plunged into cold water. ...

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  17. Mark the steel in which carbon % is highest

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  18. Mark the variety of iron which has highest melting point

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  19. In the extraction of zinc which gas is burnt in the jackets surroundin...

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  20. In the Bessemer and open-hearth process for the manufacture of steel, ...

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