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The correct order of increasing oxidisin...

The correct order of increasing oxidising power in the series is

A

`VO_(2)^(+) lt Cr_(2)O_(7)^(2-) lt MnO_(4)^(-)`

B

`Cr_(2)O_(7)^(2-)lt VO_(2)^(+) lt MnO_(4)^(-)`

C

`Cr_(2)O_(7)^(2-) ltMnO_(4)^(-) lt VO_(2)^(+)`

D

`MnO_(4)^(-) lt Cr_(2)O_(7)^(2-) ltVO_(2)^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing oxidizing power among the species \( VO_2^+ \), \( Cr_2O_7^{2-} \), and \( MnO_4^- \), we need to analyze the oxidation states of the central metal atoms in each species. ### Step-by-Step Solution: 1. **Identify the oxidation state of Vanadium in \( VO_2^+ \)**: - The oxidation state of oxygen is \(-2\). - Let the oxidation state of Vanadium be \( x \). - The equation can be set up as: \[ x + 2(-2) = +1 \] - Simplifying gives: \[ x - 4 = 1 \implies x = +5 \] 2. **Identify the oxidation state of Chromium in \( Cr_2O_7^{2-} \)**: - The oxidation state of oxygen is \(-2\). - Let the oxidation state of Chromium be \( y \). - The equation can be set up as: \[ 2y + 7(-2) = -2 \] - Simplifying gives: \[ 2y - 14 = -2 \implies 2y = 12 \implies y = +6 \] 3. **Identify the oxidation state of Manganese in \( MnO_4^- \)**: - The oxidation state of oxygen is \(-2\). - Let the oxidation state of Manganese be \( z \). - The equation can be set up as: \[ z + 4(-2) = -1 \] - Simplifying gives: \[ z - 8 = -1 \implies z = +7 \] 4. **Compare the oxidation states**: - The oxidation states obtained are: - \( VO_2^+ \): +5 - \( Cr_2O_7^{2-} \): +6 - \( MnO_4^- \): +7 - The higher the oxidation state, the stronger the oxidizing agent. Therefore, the order of increasing oxidizing power is: \[ VO_2^+ < Cr_2O_7^{2-} < MnO_4^- \] 5. **Conclusion**: - The correct order of increasing oxidizing power is: \[ VO_2^+ < Cr_2O_7^{2-} < MnO_4^- \] ### Final Answer: The correct order of increasing oxidizing power is: \[ VO_2^+ < Cr_2O_7^{2-} < MnO_4^- \]
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