Home
Class 12
CHEMISTRY
CH(3)-overset(CH(3))overset(|)underset(C...

`CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C )-CHO` shows Cannizzaro's reaction due to

A

Carbon is bounded by 3 methyl groups

B

Absence of `alpha`-hydrogen atom

C

Due to steric effect

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine why the compound \( CH_3C(CH_3)_2CHO \) (which is a branched aldehyde) shows Cannizzaro's reaction, we can follow these steps: ### Step 1: Identify the Structure of the Compound The given compound is \( CH_3C(CH_3)_2CHO \). This indicates that it is a branched aldehyde with a carbonyl group (C=O) and a formyl group (–CHO). ### Step 2: Understand Cannizzaro's Reaction Cannizzaro's reaction is a redox reaction that occurs in aldehydes that do not have alpha hydrogen atoms. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. ### Step 3: Check for Alpha Hydrogen Atoms To determine if the compound can undergo Cannizzaro's reaction, we need to check if there are any alpha hydrogen atoms present. Alpha hydrogen atoms are the hydrogen atoms attached to the carbon adjacent to the carbonyl carbon. In the structure \( CH_3C(CH_3)_2CHO \): - The carbon adjacent to the carbonyl carbon (the carbon in the –CHO group) is bonded to three methyl groups (–CH3). - Since all the adjacent carbons are fully substituted with methyl groups, there are no hydrogen atoms attached to the alpha carbon. ### Step 4: Conclusion Since the compound \( CH_3C(CH_3)_2CHO \) lacks alpha hydrogen atoms, it is unable to undergo aldol condensation and instead will undergo Cannizzaro's reaction. The steric hindrance caused by the bulky methyl groups also prevents the formation of any alpha hydrogen. ### Final Answer The compound \( CH_3C(CH_3)_2CHO \) shows Cannizzaro's reaction due to the absence of alpha hydrogen atoms. ---

To determine why the compound \( CH_3C(CH_3)_2CHO \) (which is a branched aldehyde) shows Cannizzaro's reaction, we can follow these steps: ### Step 1: Identify the Structure of the Compound The given compound is \( CH_3C(CH_3)_2CHO \). This indicates that it is a branched aldehyde with a carbonyl group (C=O) and a formyl group (–CHO). ### Step 2: Understand Cannizzaro's Reaction Cannizzaro's reaction is a redox reaction that occurs in aldehydes that do not have alpha hydrogen atoms. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise Critical Thinking Objective Questions|21 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise JEE Section Only one choice correct answer|39 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise Ordinary Thinking (Objective Questions) Preparation|43 Videos
  • ALCOHOL, PHENOL AND ETHER

    ERRORLESS |Exercise JEE SECTION (JEE Advanced 2018) More than one choice correct answer|1 Videos
  • ANALYTICAL CHEMISTRY

    ERRORLESS |Exercise JEE Section (Only One Choice Answer)|36 Videos

Similar Questions

Explore conceptually related problems

CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-C-=N

2CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CHO+NaOHrarr

In the reaction X + Y underset(5^(@)C)overset(NaOH)(rarr) CH_(3)-overset(OH)overset(|)(CH)-underset(CH_(3))underset(|)(CH)-CHO (X) and (Y) Will respectively be :

CH_(3)-Br+NaO-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)to ?

In the given reaction CH_(3)-CH_(2)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-NH_(2) overset(NaNO_(3))underset(Conc. HCl)to product(s). Product(s) will be

CH_(3)-overset(CH_(3))overset("| ")"CH"-underset(O)underset(|)C-O-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3) The common name of given ester is -

(--CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "--)_(n) is a polymer having monomer units ____________.

CH_(3)-overset(CH_(3))overset(|)C=CH-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(3) overset(NaIO4)underset(KMn04)rarrProducts The Products are:

CH_(3)-CH_(2)-overset(CHO)overset(|)(CH)-underset(CH_(3))underset(|)(CH)-CH_(3) The IUPAC name of this compound is

The IUPAC name of CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-underset(CH_(3))underset(|)(CH)-underset(I)underset(|)(CH)-CH_(2)-CH_(3) is:

ERRORLESS -ALDEHYDES AND KETONES -Ordinary Thinking (Objective Questions) Properties
  1. NaOH//H^(+) reacts with

    Text Solution

    |

  2. Acetone reacts with iodine to form iodoform in the presence of

    Text Solution

    |

  3. CH(3)-overset(CH(3))overset(|)underset(CH(3))underset(|)(C )-CHO shows...

    Text Solution

    |

  4. Aectaldehyde reacts with chlorine to give

    Text Solution

    |

  5. With which of the following reagents, carbonyl compound shows addition...

    Text Solution

    |

  6. Which one of the following gives iodoform test?

    Text Solution

    |

  7. Paraldehyde is :

    Text Solution

    |

  8. Which will not give acetamide on reaction with ammonia

    Text Solution

    |

  9. For C(6)H(5)CHO which of the following is incorrect

    Text Solution

    |

  10. When acetaldehyde is heated with Tollen's reagent which of the followi...

    Text Solution

    |

  11. If formaldehyde and KOH are heated, then we get

    Text Solution

    |

  12. Which of the following products is obtained by the oxidation of propio...

    Text Solution

    |

  13. Benzaldehyde reacts with ammonia to form

    Text Solution

    |

  14. The reagent with which both acetaldehyde and acetone react easily is

    Text Solution

    |

  15. Which compound undergoes iodoform reaction ?

    Text Solution

    |

  16. Which of the following compounds would undergo Cannizzaro's reaction

    Text Solution

    |

  17. Which gives difference between aldehyde and ketone

    Text Solution

    |

  18. C(2) H(5) CHO and (CH(3))(2) CO can be distingushed by testing with

    Text Solution

    |

  19. When CH(3)COCH(3) reacts with CI(2) and NaOH, which of the following ...

    Text Solution

    |

  20. Which of the following gives aldol condensation reaction?

    Text Solution

    |