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A compound (A) C(5)H(10) Cl(2) on hydrol...

A compound (A) `C_(5)H_(10) Cl_(2)` on hydrolysis gives `C_(5)H_(10)O` which reacts with `NH_(2)OH`, forms iodoform but does not give Fehling test (A) is :

A

`CH_(3)-overset(CI)overset(|)underset(CI)underset(|)(C )-CH_(2)-CH_(2)-CH_(3)`

B

`CH_(3)CH_(2)-overset(CI)overset(|)underset(CI)underset(|)(C )-CH_(2)CH_(3)`

C

`CH_(3)CH_(2)CH_(2)CH_(2)overset(CI)overset(|)underset(CI)(CH)`

D

`CH_(3)-overset(CI)overset(|)(CH)-overset(CI)overset(|)(CH)-CH_(2)-CH_(5)`

Text Solution

Verified by Experts

The correct Answer is:
A

As A reacts with hydroxylamine it means A may be aldehyde or ketone, but it does not react with Fehling solution hence A must be a ketone. Secondly it forms iodoform which is a characteristic reaction of methyl ketone.
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ERRORLESS -ALDEHYDES AND KETONES -Ordinary Thinking (Objective Questions) Properties
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  2. Which of the following does not reduce Fehling's solution

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  3. A compound (A) C(5)H(10) Cl(2) on hydrolysis gives C(5)H(10)O which re...

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