Home
Class 12
CHEMISTRY
Acetone and chloroform reacts to produce...

Acetone and chloroform reacts to produce

A

`CH_(3)COOC_(2)H_(5)`

B

`CH_(3)CHO`

C

`(CH_(3))_(2)C(OH)C CI_(3)`

D

`HCHO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product formed from the reaction between acetone and chloroform, we can follow these steps: ### Step 1: Identify the Reactants - Acetone (CH₃COCH₃) is a ketone with the structure: \[ \text{CH}_3 - \text{C}(\text{O}) - \text{CH}_3 \] - Chloroform (CHCl₃) is a haloalkane with the structure: \[ \text{CHCl}_3 \] ### Step 2: Understand the Reaction Mechanism - Chloroform contains a hydrogen atom that is acidic due to the presence of the electronegative chlorine atoms. - In the presence of a base, the acidic hydrogen (H) from chloroform can be removed, resulting in the formation of a chloroform anion (CCl₃⁻). ### Step 3: Formation of the Enolate Ion - The acetone can undergo deprotonation at one of its methyl groups in the presence of a strong base, forming an enolate ion: \[ \text{CH}_3 - \text{C}(\text{O}) - \text{CH}_3 \rightarrow \text{CH}_2^{-} - \text{C}(\text{O}) - \text{CH}_3 \] ### Step 4: Nucleophilic Attack - The enolate ion formed from acetone can act as a nucleophile and attack the carbon of the chloroform, resulting in the formation of a new carbon-carbon bond: \[ \text{CH}_2^{-} - \text{C}(\text{O}) - \text{CH}_3 + \text{CCl}_3 \rightarrow \text{C}(\text{CCl}_3)(\text{OH}) - \text{C}(\text{O}) - \text{CH}_3 \] ### Step 5: Final Product Formation - The final product will have a carbon atom bonded to a hydroxyl group (OH) and a trichloromethyl group (CCl₃) along with the remaining acetone structure: \[ \text{C}(\text{CCl}_3)(\text{OH}) - \text{C}(\text{O}) - \text{CH}_3 \] ### Conclusion The product formed from the reaction of acetone and chloroform is: \[ \text{C}(\text{CCl}_3)(\text{OH}) - \text{C}(\text{O}) - \text{CH}_3 \]

To determine the product formed from the reaction between acetone and chloroform, we can follow these steps: ### Step 1: Identify the Reactants - Acetone (CH₃COCH₃) is a ketone with the structure: \[ \text{CH}_3 - \text{C}(\text{O}) - \text{CH}_3 \] - Chloroform (CHCl₃) is a haloalkane with the structure: ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise Critical Thinking Objective Questions|21 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise JEE Section Only one choice correct answer|39 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS |Exercise Ordinary Thinking (Objective Questions) Preparation|43 Videos
  • ALCOHOL, PHENOL AND ETHER

    ERRORLESS |Exercise JEE SECTION (JEE Advanced 2018) More than one choice correct answer|1 Videos
  • ANALYTICAL CHEMISTRY

    ERRORLESS |Exercise JEE Section (Only One Choice Answer)|36 Videos

Similar Questions

Explore conceptually related problems

When acetone and chloroform are mixed, hydrogen bonding takes place between them. Such a liquid pair will cause

When acetone and chloroform are mixed, hydrogen bonding takes placce between them, such a liquid pair will cause :

What is the expected deviation from solution behawhen acetone and chloroform are mixed to form a solution ?

When acetone and chloroform are mixed together , hydrogen bonds are formed between them. Which of the following statements is correct about the solution made by mixing acetone and chloroform ?

Name the product obtained when chloroform reacts with (a) nitric acid (b) silver powder (C) aniline in the presence of alcoholic KOH (d) acetone.

Name the product obtained when chloroform reacts with (a) nitric acid (b) silver powder (C) aniline in the presence of alcoholic KOH (d) acetone.

When acetone and chloroform are mixed together, which of the following observations is correct ?

When acetone and chloroform are mixed together, H - bonding takes place between them. Such a liquid pair shows

The chloroform reacts with NaOH to give

(A) The dissolution of acetone in chloroform is an exothermic process. (R) H-bonding occurs between acetone and chloroform molecules on mixing the two.

ERRORLESS -ALDEHYDES AND KETONES -Ordinary Thinking (Objective Questions) Properties
  1. Which of the following reagents is used to distinguish acetone and ace...

    Text Solution

    |

  2. A underset(800^(@)C )overset(Delta)(rarr) CH(2) = C = O , Reactant ' A...

    Text Solution

    |

  3. Acetone and chloroform reacts to produce

    Text Solution

    |

  4. Formalin is

    Text Solution

    |

  5. Benedict's solution is not reduced by

    Text Solution

    |

  6. Which one of the following is reduced with zinc and hydrochloric acid ...

    Text Solution

    |

  7. The increasing order of the rate of HCN addition to compound A-D is ...

    Text Solution

    |

  8. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

    Text Solution

    |

  9. Trichloroacetaldehyde was subjected to cannizzaro's reaction by using ...

    Text Solution

    |

  10. In the gives transformation, which the following is the most appropria...

    Text Solution

    |

  11. What is the reaction of acetaldehyde with concentraed sulphuric acid

    Text Solution

    |

  12. Identify the correct statement

    Text Solution

    |

  13. A Wittig reaction with an aldehyde gives

    Text Solution

    |

  14. Which of the donot react with fehling solution ?

    Text Solution

    |

  15. Dimethyl ketones are usually characterised through

    Text Solution

    |

  16. Treatment of propionaldehyde with dilute NaOH solution gives

    Text Solution

    |

  17. The aldehyde which react with NaOH to produce an alcohol and sodium sa...

    Text Solution

    |

  18. Cyanohydrin of which of the following forms lactic acid

    Text Solution

    |

  19. Which of the following is used to detect aldehydes

    Text Solution

    |

  20. Which of the following does not give brick red ppt. with Fehling solut...

    Text Solution

    |