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What is the reaction of acetaldehyde wit...

What is the reaction of acetaldehyde with concentraed sulphuric acid

A

No reaction

B

Decomposition

C

Charred to black residue

D

Polymerisation

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The correct Answer is:
### Step-by-Step Solution 1. **Identify the Reactants**: The reaction involves acetaldehyde (CH₃CHO) and concentrated sulfuric acid (H₂SO₄). 2. **Understand the Role of Concentrated Sulfuric Acid**: Concentrated sulfuric acid acts as a dehydrating agent. This means it can remove water (H₂O) from the acetaldehyde, leading to dehydration. 3. **Initial Protonation**: When acetaldehyde reacts with concentrated sulfuric acid, the carbonyl oxygen of acetaldehyde can be protonated by H⁺ from sulfuric acid, forming a more reactive species. \[ \text{CH}_3\text{CHO} + \text{H}^+ \rightarrow \text{CH}_3\text{C(OH)}^+ \] 4. **Formation of Carbocation**: The protonation leads to the formation of a carbocation, which is a positively charged carbon species. This carbocation can further react with another molecule of acetaldehyde. 5. **Nucleophilic Attack**: The carbocation formed can act as an electrophile and can react with another acetaldehyde molecule. The nucleophilic carbon of another acetaldehyde attacks the carbocation. \[ \text{CH}_3\text{C}^+ + \text{CH}_3\text{CHO} \rightarrow \text{CH}_3\text{C(OH)(CH}_3\text{)}\text{CHO} \] 6. **Polymerization**: The reaction can lead to polymerization, where multiple acetaldehyde units can join together. This can form either linear or cyclic structures depending on the conditions and the number of acetaldehyde molecules involved. 7. **Final Products**: The final products may include oligomers or polymers of acetaldehyde, which can be in the form of linear chains or cyclic compounds. The exact structure will depend on the reaction conditions.

### Step-by-Step Solution 1. **Identify the Reactants**: The reaction involves acetaldehyde (CH₃CHO) and concentrated sulfuric acid (H₂SO₄). 2. **Understand the Role of Concentrated Sulfuric Acid**: Concentrated sulfuric acid acts as a dehydrating agent. This means it can remove water (H₂O) from the acetaldehyde, leading to dehydration. 3. **Initial Protonation**: When acetaldehyde reacts with concentrated sulfuric acid, the carbonyl oxygen of acetaldehyde can be protonated by H⁺ from sulfuric acid, forming a more reactive species. ...
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ERRORLESS -ALDEHYDES AND KETONES -Ordinary Thinking (Objective Questions) Properties
  1. Trichloroacetaldehyde was subjected to cannizzaro's reaction by using ...

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  2. In the gives transformation, which the following is the most appropria...

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  3. What is the reaction of acetaldehyde with concentraed sulphuric acid

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  4. Identify the correct statement

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  5. A Wittig reaction with an aldehyde gives

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  6. Which of the donot react with fehling solution ?

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  7. Dimethyl ketones are usually characterised through

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  8. Treatment of propionaldehyde with dilute NaOH solution gives

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  9. The aldehyde which react with NaOH to produce an alcohol and sodium sa...

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  10. Cyanohydrin of which of the following forms lactic acid

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  11. Which of the following is used to detect aldehydes

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  12. Which of the following does not give brick red ppt. with Fehling solut...

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  13. Ararr(CH(3))(2)C = CHCOCH(3), A is

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  14. The end prduct in the Cannizaro's reaction of benzaldehyde is

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  15. Which one of the following does not form sodium bisulphite addition pr...

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  16. Which is most reactive of the following ?

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  17. Which of the following does not undergo Cannizzaro's reaction ?

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  18. A ketone gives a yellow precipitate, when treated with I(2)in an alkal...

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  19. The order of susceptibility of nucleophilic attack on aldehydes follow...

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  20. OHC-CHOoverset(OH^(-))toHOH(2)C-COOH. The reaction given is

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