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Which one of the following does not form...

Which one of the following does not form sodium bisulphite addition product with sodium bisulphite solution

A

`CH_(3)OH`

B

`C_(6)H_(5)COCH_(3)`

C

`C_(6)H_(5)CHO`

D

`CH_(3)CHO`

Text Solution

Verified by Experts

The correct Answer is:
B
Crystalline solid derivatives are formed when aldehydes or ketones are shaken with saturated aqueous solution of sodium bisulphite, but sodium bisulphite is a bigger nucleophile so, all ketones do not give this test. Only aliphaic methyl ketones form addition product with sodium bisulphite.
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ERRORLESS -ALDEHYDES AND KETONES -Ordinary Thinking (Objective Questions) Properties
  1. Ararr(CH(3))(2)C = CHCOCH(3), A is

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  2. The end prduct in the Cannizaro's reaction of benzaldehyde is

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  3. Which one of the following does not form sodium bisulphite addition pr...

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  4. Which is most reactive of the following ?

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  5. Which of the following does not undergo Cannizzaro's reaction ?

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  6. A ketone gives a yellow precipitate, when treated with I(2)in an alkal...

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  7. The order of susceptibility of nucleophilic attack on aldehydes follow...

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  8. OHC-CHOoverset(OH^(-))toHOH(2)C-COOH. The reaction given is

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  9. HCHO and HCOOH are detected by

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  10. Which can undergo haloform reaction ?

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  11. underset(aq.)(3HCHO) overset("cooled")hArr X.X is

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  12. An aromatic compound 'X' with molecular formula C(9)H(10)O gives the f...

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  13. Aldehydes and ketones give addition reaction with

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  14. Only an aldehyde having….can undergo the aldol condensation

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  15. Identify the organic compound which on heating with strong solution of...

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  16. Benzaldehyde and acetone can be best distinguished using ……..

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  17. The correct sequence of steps involved in the mechanism of cannizzaro'...

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  18. An organic compound 'A' burns with a sooty flame. It is negative towar...

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  19. Methyl ketones are usually characterised through

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  20. Which of the following compounds is most reactive towards nucleophilic...

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