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Match the compounds given in List I with...

Match the compounds given in List I with List II and select the suitable option using the code given below
`{:(List I,List II),((A)"Benzaldehyde",(i)"Phenolphthalein"),((B)"Phthalic anhydride",(ii)"Benzoin condensation"),((C)"Phenyl benzoate",(iii)"Oil of wintergreen"),((D)"Methyl salicylate",(iv)"Fire rearrangement"):}`
Code

A

`{:((A),(B),(C),(D).),((ii),(iii),(iv),(i).):}`

B

`{:((A),(B),(C),(D).),((ii),(i),(iv),(iii).):}`

C

`{:((A),(B),(C),(D).),((iv),(i),(iii),(ii).):}`

D

`{:((A),(B),(C),(D).),((iv),(ii),(iii),(i).):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the matching question, we will analyze each compound in List I and determine which compound from List II corresponds to it. ### Step-by-Step Solution: 1. **Identify Compound A: Benzaldehyde** - Benzaldehyde is known to undergo a reaction called **Benzoin condensation**. In this reaction, benzaldehyde reacts with cyanide ions (KCN) to form benzoin. - **Match:** A (Benzaldehyde) → (ii) Benzoin condensation 2. **Identify Compound B: Phthalic Anhydride** - Phthalic anhydride is used in the synthesis of **Phenolphthalein**. This compound is formed through the reaction of phthalic anhydride with phenol in the presence of an acid catalyst. - **Match:** B (Phthalic anhydride) → (i) Phenolphthalein 3. **Identify Compound C: Phenyl Benzoate** - Phenyl benzoate can undergo a reaction known as the **Fries rearrangement**. In this reaction, phenyl benzoate is treated with a Lewis acid, leading to the formation of ortho- and para-hydroxybenzophenone. - **Match:** C (Phenyl benzoate) → (iv) Fries rearrangement 4. **Identify Compound D: Methyl Salicylate** - Methyl salicylate is commonly referred to as **Oil of wintergreen**. It is a compound that is used for its aromatic properties and is derived from salicylic acid. - **Match:** D (Methyl salicylate) → (iii) Oil of wintergreen ### Final Matches: - A → (ii) Benzoin condensation - B → (i) Phenolphthalein - C → (iv) Fries rearrangement - D → (iii) Oil of wintergreen ### Code: The final matching can be represented as: - A → (ii) - B → (i) - C → (iv) - D → (iii)

To solve the matching question, we will analyze each compound in List I and determine which compound from List II corresponds to it. ### Step-by-Step Solution: 1. **Identify Compound A: Benzaldehyde** - Benzaldehyde is known to undergo a reaction called **Benzoin condensation**. In this reaction, benzaldehyde reacts with cyanide ions (KCN) to form benzoin. - **Match:** A (Benzaldehyde) → (ii) Benzoin condensation ...
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ERRORLESS -ALDEHYDES AND KETONES -Critical Thinking Objective Questions
  1. The major organic product formed from the following reaction

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  2. Match the compounds given in List I with List II and select the suitab...

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  3. Benzophenone does not react with

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  4. Aldehyde and ketones can decolourise

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  5. Which of the following pairs can be distinguished by sodium hypoiodite...

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  6. Consider the following reactions I. H(3)C CI(3) overset(OH^(Theta))r...

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  7. Identify the product (E ) in the following sequence of reactions

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  8. On vigorous oxidation by permanganate solution (CH(3))(2)C=CH-CH(2)CH(...

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  9. Which is not true about acetophenone ?

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  10. A compound containing only carbon, hydrogen and oxygen has molecular m...

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  11. The key step in cannizzaro's reaction is the intermolecular shift of

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  12. One of the following named reaction is an example of "disproportionati...

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  13. CH(3)-CH(2)-overset(O)overset(||)(C )-OC(2)H(5) overset(Naoverset(**)(...

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  14. In which of the following reactions, the product obtained is chiral ?

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  15. The conversion of acetophenone to acetanilide is best accompanied by u...

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  16. Which of the following will not give iodoform test ?

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  17. Which fo the following statements regarding chemical properties of ace...

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  18. An organic compound 'A' has the molecular formula C(3)H(6)O, it underg...

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  19. Which alkene is formed from the following ylide carbonyl pair CH(3)C...

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  20. The most reactive compound towards formation of cyanohydrin on treatme...

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