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On reduction with Na-Hg and water a carb...

On reduction with Na-Hg and water a carbohydrate gives a mixture of sorbitol and mannitol. The carbohydrate can be

A

Glucose

B

fructose

C

cane sugar

D

lactose

Text Solution

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The correct Answer is:
To determine which carbohydrate gives a mixture of sorbitol and mannitol upon reduction with Na-Hg and water, we can follow these steps: ### Step 1: Understand the Reduction Process Reduction of carbohydrates typically involves converting carbonyl groups (aldehydes or ketones) into alcohols. In this case, we are looking for a carbohydrate that, when reduced, yields both sorbitol and mannitol. **Hint:** Remember that sorbitol and mannitol are both sugar alcohols derived from the reduction of sugars. ### Step 2: Identify Sorbitol and Mannitol Sorbitol (D-sorbitol) and mannitol (D-mannitol) are both hexitols (six-carbon sugar alcohols). Their structures can be represented as follows: - Sorbitol: C6H14O6 - Mannitol: C6H14O6 Both have the same molecular formula but differ in the arrangement of hydroxyl groups. **Hint:** Look at the structural differences between sorbitol and mannitol to understand how they are derived from sugars. ### Step 3: Determine the Source Carbohydrate The carbohydrate that can yield both sorbitol and mannitol upon reduction is fructose. Fructose is a ketohexose, which means it contains a ketone group. When fructose is reduced, it can form both sorbitol and mannitol. **Hint:** Recall that fructose has a ketone functional group, which can lead to the formation of both sugar alcohols upon reduction. ### Step 4: Write the Reaction When fructose (C6H12O6) is reduced using Na-Hg and water, it can be converted into a mixture of sorbitol and mannitol. The reduction process involves the addition of hydrogen atoms to the carbonyl group, resulting in the formation of alcohol groups. **Hint:** Visualize the reduction process by drawing the structural formulas of fructose, sorbitol, and mannitol to see how the transformation occurs. ### Conclusion The carbohydrate that gives a mixture of sorbitol and mannitol upon reduction with Na-Hg and water is **fructose**. **Final Answer:** The carbohydrate can be fructose.

To determine which carbohydrate gives a mixture of sorbitol and mannitol upon reduction with Na-Hg and water, we can follow these steps: ### Step 1: Understand the Reduction Process Reduction of carbohydrates typically involves converting carbonyl groups (aldehydes or ketones) into alcohols. In this case, we are looking for a carbohydrate that, when reduced, yields both sorbitol and mannitol. **Hint:** Remember that sorbitol and mannitol are both sugar alcohols derived from the reduction of sugars. ### Step 2: Identify Sorbitol and Mannitol ...
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