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The rate constant of a first order react...

The rate constant of a first order reaction is `60s^(-1)`. How much time it will take to reduce `75%` of its original concentration ?

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To solve the problem, we need to determine how much time it takes for a first-order reaction to reduce its original concentration by 75%. ### Step-by-Step Solution: 1. **Understand the Reaction Order**: The reaction is first-order, which means the rate of reaction is directly proportional to the concentration of the reactant. 2. **Identify the Given Data**: - Rate constant (k) = 60 s⁻¹ - Reduction in concentration = 75% - Therefore, the remaining concentration after 75% reduction = 100% - 75% = 25% 3. **Use the First-Order Kinetics Formula**: The integrated rate law for a first-order reaction is given by: \[ t = \frac{2.303}{k} \log \left( \frac{[A_0]}{[A_t]} \right) \] Where: - \( [A_0] \) = initial concentration - \( [A_t] \) = concentration at time t - \( k \) = rate constant - \( t \) = time 4. **Substitute the Values**: - Let’s assume the initial concentration \( [A_0] = 100 \) (in arbitrary units). - The concentration at time t \( [A_t] = 25 \) (after 75% reduction). - Substitute these values into the formula: \[ t = \frac{2.303}{60} \log \left( \frac{100}{25} \right) \] 5. **Calculate the Logarithm**: \[ \frac{100}{25} = 4 \] Therefore: \[ \log(4) \approx 0.602 \] 6. **Calculate Time (t)**: Now substituting the values back into the equation: \[ t = \frac{2.303}{60} \times 0.602 \] \[ t \approx \frac{1.384}{60} \] \[ t \approx 0.02307 \text{ seconds} \] ### Final Answer: The time it will take to reduce 75% of the original concentration is approximately **0.0231 seconds**.

To solve the problem, we need to determine how much time it takes for a first-order reaction to reduce its original concentration by 75%. ### Step-by-Step Solution: 1. **Understand the Reaction Order**: The reaction is first-order, which means the rate of reaction is directly proportional to the concentration of the reactant. 2. **Identify the Given Data**: ...
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