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What are the units of the rate constant ...

What are the units of the rate constant of a pseudo unimolecular reaction ?

Text Solution

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`k'=k[H_(2)O]:.(k')/([H_(2)O])=(min^(-1))/(molL^(-1))=Lmol^(-1)min^(-1)`
Thus, it has the units of a second order reaction.
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Knowledge Check

  • In pseudo-unimolecular reactions :

    A
    one of the reactants is present in large excess
    B
    both reactants have some concentration
    C
    both the reactants are present in low concentration
    D
    one of the reactants is less reactive
  • For a unimolecular reaction

    A
    the molecularity and order of a reaction is one
    B
    the molecularity of the reaction is one while their order is zero
    C
    two reacting speies are involved in the rate determining step
    D
    the molecularity and order of the slowest step of the reaction is euqal to one
  • An example of a pseudo unimolecular reaction is

    A
    Dissociation of hydrogen iodide
    B
    Hydrolysis of methyl acetate in dilute solution
    C
    Dissociation of phosphorus pentachloride
    D
    Decompoition of hydrogen peroxide
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