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The volume of nitrogen gas Um (measured ...

The volume of nitrogen gas Um (measured at STP) required to cover a sample of silica get with a mono-molecular layer is `129 cm^(3) g^(-1)` of gel. Calculate the surface area per gram of the gel if each nitrogen molecule occupies `16.2 xx 10^(-20) m^(2).`

Text Solution

Verified by Experts

`22400cm^(3)` or `N_(2)` at S.T.P. contain `=6.022xx10^(23)` molecules
`therefore 129 cm ^(3)` of `N_(2)` at S.T.P. will contain `=(6.022xx10^(23)xx129)/(22400)=3.468xx10^(21)` molecules
Area occupied by a single molecule `=16.2xx10^(-20)m^(2)`
`therefore` Area occupied by `6.468 xx10^(21)` molecules of `N_(2)=(16.2 xx10^(-20))xx(3.468xx10^(21))m^(2)=561.8m^(2)`
`therefore` Surface area per gram of gel `=561.8m^(2).`
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