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Bismuth is a strong oxidizing agent in t...

Bismuth is a strong oxidizing agent in the pentavalent state. Or pentavalent bismuth is a strong oxidizing agent.

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Since the inert pair effect is very prominent in Bi, therefore, its +5 oxidation state is much less stable than its +3 oxidation state. In other words, bismuth in the pentavalent state can easily accept two electrons and thus gets reduced to more stable trivalent bismuth.
`Bi^(5+) + 2 e^(-) rarr Bi^(3+)`
Therefore, Bi in the pentavalent state acts as a strong oxidising agent.
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PRADEEP-P-BLOCK ELEMENTS -CONCEPTUAL QUESTION
  1. Tendency to form pentahalides decreases down the group 15 of the perio...

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  2. Give the chemical reaction to support that +5 oxidation state of Bi is...

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  3. Bismuth is a strong oxidizing agent in the pentavalent state. Or penta...

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  4. Explain why both N and Bi do not form pentahalides while phosphorus do...

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  5. NH(3) has higher boiling point than PH(3). Give reason.

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  6. Although nitrogen and chlorine have very nearly same electronegativity...

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  7. Although fluorine is much more electronegative than hydrogen yet the d...

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  8. NCl(3) is an endothermic compound while NF(3) is an exothermic compou...

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  9. Unlike phosphorus, nitrogen show little tendency for catenation. Or ...

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  10. Ammonia is a good complexing agent. Give reasons. Or Ammonia acts as...

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  11. Why is N(2)O(5) more acidic than N(2)O(3) ?

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  12. Give reasons for the following : (i) NO (Nitric oxide) is paramagnet...

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  13. In the structure of HNO(3), why is N-O bond (121 pm) shorter than N-OH...

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  14. Compound that acts as oxidant as well as reductant

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  15. Why is red phosphorus less reactive than white phosphorus ?

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  16. PCl(5) is ionic in nature in the solid state. Give reasons. Or Solid...

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  17. Draw the structure of PCl(5). Or Solid PCl(5) is ionic in nature.

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  18. Give chemical reaction in support of the statement that all the bonds ...

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  19. H(3)PO(3) is diprotic (or dibasic). Why ? Or What is the basicity of...

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  20. The electron gain enthalpy with negative sign for oxygen (− 141 KJ mol...

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