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All the bonds in SF(4) are not equivalen...

All the bonds in `SF_(4)` are not equivalent. Why ?

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S in `SF_(4)` is `sp^(3)` d-hybridized. Therefore, `SF_(4)` has trigonal bipyramid structure or see-saw geometry. Two of the S-F bonds occypy equatorial positions and are 155 pm long while the third equatorial position is occupied by a lone pair of electrons. The remaining two S-F bonds occypy axial positions and are little longer (165 pm) due to repulsions between the axial bond pairs and the equatorial lone pair. Thus, all the four S-F bonds in `SF_(4)` are not equivalent.
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PRADEEP-P-BLOCK ELEMENTS -CONCEPTUAL QUESTION
  1. H(2)S is a stronger acid than H(2)O. Explain

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  2. Give reasons for the following observations : Why SF(4) undergoes hy...

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  3. All the bonds in SF(4) are not equivalent. Why ?

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  4. Sulphur hexafluoride is used as a gaseous electrical insulator.

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  5. (a) Suggest a quantitative method for estimation of a gas which protec...

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  6. Sulphur disappears when boiled with an aqueous solution of sodium sulp...

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  7. Draw the structure of : SO(3)^(2-)

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  8. Give a chemical reaction in the support of the observation that sulphu...

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  9. Electron gain enthalpies of halogens are largely negative. Explain.

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  10. The negative value of electron gain enthalpy is less for fluorine than...

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  11. F2 has lower bond dissociation enthalpy than Cl2. Why?

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  12. I(2) is more soluble in KI than in water. Why ?

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  13. Why fluorine does not exhibit any positive oxidation state?

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  14. Fluoride ion has higher hydration enthalpy than chloride ion. Give rea...

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  15. Among halogens, F(2) is the strongest oxidising agent. Or F(2) is a ...

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  16. F(2) is a stronger oxidising agent than Cl(2)

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  17. Addition of Cl(2) to KI solution gives it a brown colour but excess of...

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  18. Give chemical reaction in support of the observation that iodide ions ...

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  19. Arrange the following in the decreasing order of their boiling points ...

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  20. (i) Hydrogen fluoride is a weaker acid than hydrogen chloride in aqueo...

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