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Why are pentahalides more covalent than ...

Why are pentahalides more covalent than trihalides?

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The elements of group 15 have five electrons (two in the s- and threein the p-orbitals) in their respective valence shells. Since its is difficult to lose all the three electrons to form `E^(3+)` or even more difficult to lose all the five valence electrons (two s- and three p-) to form `E^(5+)` ions, therefore, higher elements have no tendency to form ionic compounds. Instead they form covalent compounds by sharing of electrons.
Since elements in the +5 oxidation state have less tendency to lose electrons than in the +3 oxidation state, therefore, elements in the +5 oxidation state have more tendency to share electrons than in the +3 oxidation state. Thus, elements in the +5 oxidation state are more covalent than in the +3 oxidation state. In other words, pentahalides are more covalent than trihalides.
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PRADEEP-P-BLOCK ELEMENTS -NCERT QUESTIONS AND EXERCISES WITH ANSWERS
  1. Why do noble gases have low boiling points ?

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  2. Does the hydrolysis of XeF(6) leads to a redox reaction?

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  3. Why are pentahalides more covalent than trihalides?

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  4. Why is BiH(3) the strongest reducing agent amongst all the hydrides of...

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  5. Why is N(2) less reactive at room temperature ?

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  6. Mention the conditions required to maximise the yield of ammonia.

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  7. How does ammonia react with a solution of Cu^(2+)?

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  8. What is the covalence of nitrogen in N(2)O(5) ?

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  9. Bond angle in PH(4)^(+) is higher than that in PH(3).Why ?

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  10. What happens when white phosphorus is heated with concentrated NaOH so...

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  11. What happens when PCl(5) is heated ?

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  12. Write the balanced equation for the hydrolytic reaction of PCl(5) in h...

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  13. What is the basicity of H(3)PO(4) ?

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  14. What happens when H(3) PO(3) is heated ?

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  15. List the important sources of sulphur.

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  16. Write the order of thermal stability of the hydrides of group 16 eleme...

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  17. Why is H(2)O a liquid and H(2)S a gas ?

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  18. Which of the following does not react with oxygen directly? Zn,Ti,Pt,F...

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  19. Complete the following reactions: (i) C(2) H(4) + O(2) to (ii)...

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  20. Why does O3 act as a powerful oxidising agent?

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