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Why does the reactivity of nitrogen diff...

Why does the reactivity of nitrogen differ from phosphorus?

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Nitrogen exists as a diatomic molecule (N = N). Due to the presence of a triple bond between the two N-atoms, the bond dissociationn energy is large (941.4 kJ `mol^(-1)`). As a result, nitrogen is inert and unreactive in its elemental state.
In contrast, white or yellow phosphorus exist as a tetra-atomic molecule `(P_(4))`. Since the P-P single bond is much weaker (213 kJ `mol^(-1)`) than N = N triple bond (941.4 kJ `mol^(-1)`), therefore, phosphorus is much more reactive than nitrogen.
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Knowledge Check

  • The low reactivity of nitrogen is due to

    A
    small atomic radius
    B
    high electroguativity
    C
    stable configuration
    D
    high dissociation energy
  • The atomicity of nitrogen and phosphorus is respectively

    A
    2 and 2
    B
    2 and 3
    C
    2 and 4
    D
    2 and 5
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