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Standard reduction potentials of the hal...

Standard reduction potentials of the half reactions are given below
`{:(F_(2(g))+2e^(-) rarr 2F^(-)""_((aq)),,E^(@)=+2.85V), (Cl_(2(g))+2e^(-) rarr 2Cl^(-)""_((aq)),, E^(@)=+1.36V), (Br_(2(l))+2e^(-) rarr 2Br^(-)""_((aq)),,E^(@)=+1.06V), (l_(2(s))+2e^(-) rarr 2l^(-)""_((aq)),, E^(@)=+0.53V):}`
The strongest oxidising and reducing agents respectively are

A

`F_(2) and I^(-)`

B

`Br_(2) and Cl^(-)`

C

`Cl_(2) and Br^(-)`

D

`Cl_(2) and I_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Since `F_(2)` has the highest electrode potential, therefore, it is the strongest oxidising agent and `F^(-)` is the weakest reducing agent.
Further, since `I_(2)` has the lowest electrode potential, therefore, it is the weakest oxidising agent and conversely `I^(-)` is the strongest reducing agent. Thus, option (a) is correct.
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Standard reduction potentails of the half reactions are given below: F_(2)(g)+2e^(-) rarr 2F^(-)(aq.),, E^(ɵ)= +2.87 Cl_(2)(g)+2e^(-) rarr 2Cl^(-)(aq.),, E^(ɵ)= +1.36 V Br_(2)(g)+2e^(-) rarr 2Br^(-)(aq.),, E^(ɵ)= +1.09 V I_(2)(s)+2e^(-) rarr 2l^(-)(aq.),, E^(ɵ)= +0.54 V The strongest oxidizing and reducing agents respectively are:

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