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Assertion. Reaction of SO(2) and H(2)S i...

Assertion. Reaction of `SO_(2)` and `H_(2)S` in the presence of `Fe_(2)O_(3)` catalyst gives elemental sulphur.
Reason. `SO_(2)` is a reducing agent.

A

If both assertion and reason are true, and reason is the correct explanation of the assertion.

B

If both assertion and reason are ture, but reason is not the correct explanantion of the assertion.

C

If assertion is true, but reason is false.

D

If both assertion and reason are false

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The correct Answer is:
To analyze the given assertion and reason, we will break down the information step by step. ### Step 1: Understanding the Assertion The assertion states that the reaction of \( SO_2 \) and \( H_2S \) in the presence of \( Fe_2O_3 \) catalyst gives elemental sulfur. **Chemical Reaction:** The reaction can be represented as: \[ 2 H_2S + SO_2 \xrightarrow{Fe_2O_3} 2 H_2O + S \] This indicates that sulfur is produced as a product of the reaction. ### Step 2: Analyzing the Reaction In this reaction, \( H_2S \) acts as a reducing agent, while \( SO_2 \) is being reduced to elemental sulfur (S). - **Oxidation State Changes:** - In \( H_2S \), sulfur has an oxidation state of -2. - In \( SO_2 \), sulfur has an oxidation state of +4. - In elemental sulfur (S), the oxidation state is 0. The \( H_2S \) reduces \( SO_2 \) to elemental sulfur, which confirms that the assertion is correct. ### Step 3: Understanding the Reason The reason states that \( SO_2 \) is a reducing agent. - **Role of \( SO_2 \):** While \( SO_2 \) can act as a reducing agent in some reactions, it is primarily known as an oxidizing agent in this context because it accepts electrons from \( H_2S \). Thus, while \( SO_2 \) can exhibit reducing properties, it is not accurate to classify it solely as a reducing agent in this reaction. ### Conclusion - **Assertion:** True (The reaction produces elemental sulfur). - **Reason:** True (But not a correct explanation for the assertion). ### Final Statement The assertion is true, and the reason is also true, but the reason does not correctly explain the assertion. ---

To analyze the given assertion and reason, we will break down the information step by step. ### Step 1: Understanding the Assertion The assertion states that the reaction of \( SO_2 \) and \( H_2S \) in the presence of \( Fe_2O_3 \) catalyst gives elemental sulfur. **Chemical Reaction:** The reaction can be represented as: \[ 2 H_2S + SO_2 \xrightarrow{Fe_2O_3} 2 H_2O + S \] ...
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