Home
Class 12
CHEMISTRY
Assertion. The HF(2)^(-) ion exists in t...

Assertion. The `HF_(2)^(-)` ion exists in the solid state and also in liquid state but not in aqueous solution.
Reason. The magnitude of hydrogen bonds in between HF-HF molecule is weaker than that in between HF and `H_(2)O` molecules.

A

If both assertion and reason are true, and reason is the correct explanation of the assertion.

B

If both assertion and reason are ture, but reason is not the correct explanantion of the assertion.

C

If assertion is true, but reason is false.

D

If both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the concepts involved step by step. ### Step 1: Understanding the Assertion The assertion states that the `HF2^(-)` ion exists in the solid state and liquid state but not in aqueous solution. **Explanation**: - The `HF2^(-)` ion is formed by the association of two HF molecules through hydrogen bonding. - In the solid state, these ions can pack closely together, allowing for stable hydrogen bonding interactions. - In the liquid state, the ion can still exist due to the presence of strong intermolecular forces. - However, in aqueous solution, the presence of water molecules may disrupt the hydrogen bonding network between HF molecules, leading to the instability or non-existence of the `HF2^(-)` ion. ### Step 2: Understanding the Reason The reason provided states that the magnitude of hydrogen bonds between HF-HF molecules is weaker than that between HF and `H2O` molecules. **Explanation**: - Hydrogen bonds between HF molecules are indeed strong, but when HF interacts with water, the hydrogen bonding can be even stronger due to the highly polar nature of water. - Water can stabilize the HF molecules through its own hydrogen bonding, which can lead to the breakdown of the `HF2^(-)` ion in an aqueous environment. ### Step 3: Evaluating the Assertion and Reason Now, we need to evaluate if the assertion and reason are true or false and if the reason correctly explains the assertion. 1. **Assertion**: True. The `HF2^(-)` ion exists in solid and liquid states but not in aqueous solution. 2. **Reason**: True. The hydrogen bonds between HF and water are stronger than those between HF and HF. 3. **Connection**: The reason does explain why the `HF2^(-)` ion does not exist in aqueous solution, as the stronger hydrogen bonding with water destabilizes the ion. ### Conclusion Both the assertion and reason are true, and the reason correctly explains the assertion. ### Final Answer - **Assertion**: True - **Reason**: True - **Explanation**: The `HF2^(-)` ion can exist in solid and liquid states due to strong hydrogen bonding between HF molecules, but in aqueous solution, the stronger hydrogen bonding with water destabilizes the ion. ---

To analyze the assertion and reason provided in the question, we will break down the concepts involved step by step. ### Step 1: Understanding the Assertion The assertion states that the `HF2^(-)` ion exists in the solid state and liquid state but not in aqueous solution. **Explanation**: - The `HF2^(-)` ion is formed by the association of two HF molecules through hydrogen bonding. - In the solid state, these ions can pack closely together, allowing for stable hydrogen bonding interactions. ...
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos
  • P-BLOCK ELEMENTS

    PRADEEP|Exercise INTEGER TYPE QUESTIONS|15 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|27 Videos
  • POLYMERS

    PRADEEP|Exercise IMPORTANT Questions (For Board Examination)|27 Videos

Similar Questions

Explore conceptually related problems

The HF_(2)^(Θ) ion solid state and in liquid HF but not in the dilute aqueous solution In aqueous solution

The HF_(2)^(Θ) ion solid state and in liquid HF but not in the dilute aqueous solution Energy of H-bond is maximum in .

The HF_(2)^(Θ) ion solid state and in liquid HF but not in the dilute aqueous solution At 300 K and 1.00 atm, the density of HF is 3.17 gL^(-1) We conclude that there is a .

The HF_(2)^(Θ) ion solid state and in liquid HF but not in the dilute aqueous solution HF_(2)^(Θ) exists in solid state and in liquid HF because HF_(2)^(Θ) ions are held together by .

Name two intermolecular forces that exist between HF molecules in liquid state.

PRADEEP-P-BLOCK ELEMENTS -ASSERTION-REASON TYPE QUESTIONS
  1. Assertion: On cooling, the brown colour of nitrogen dioxide disappears...

    Text Solution

    |

  2. Assertion : P(4) is more reactive than N(2) Reason: P-P single bond ...

    Text Solution

    |

  3. Assertion (A) Elementary phosphorus exists in three principal allotrop...

    Text Solution

    |

  4. Assertion : H(3)PO(3) is a diabasic acid. Reason: There are two H at...

    Text Solution

    |

  5. Assertion (A) H(2)O is the only hydride of group - 16 which is liquid ...

    Text Solution

    |

  6. Assertion : H-S-H bond angle in H(2)S is closer to 90^(@) but H-O-H b...

    Text Solution

    |

  7. Asseration: SeCl(4), does not havea tetrahedral structure. Reason: S...

    Text Solution

    |

  8. Assertion :The S-S-S bond in S(8) molecule is 105^(@). Reason :S(8)...

    Text Solution

    |

  9. Assertion:All F-S-F angle in SF(4) is greater tha 90^(@) but than180^(...

    Text Solution

    |

  10. Assertion. Reaction of SO(2) and H(2)S in the presence of Fe(2)O(3) ca...

    Text Solution

    |

  11. Assertion. Ozone is a powerful oxidising agent in comparison to O(2) ...

    Text Solution

    |

  12. Asseration: F-F bond in F(2) molecule is strong. Reason: F-atom is s...

    Text Solution

    |

  13. Assertion. The O-O bond length in H(2)O(2) is shorter than that of O(2...

    Text Solution

    |

  14. Assertion. F(2) has high reactivity. Reason. F-F bond has low bond d...

    Text Solution

    |

  15. Assertion. SiF(6)^(2-) is known but SiCl(6)^(2-) is not. Reason. Siz...

    Text Solution

    |

  16. Assertion. HOF bond angle is higher than HOCl bond angle in HOX. Rea...

    Text Solution

    |

  17. Assertion. The HF(2)^(-) ion exists in the solid state and also in liq...

    Text Solution

    |

  18. Assertion: HClO(4) is a stronger acid than HClO(3). Reason: Oxidatio...

    Text Solution

    |

  19. Assertion : Noble gases have positive electron gain enthalpy. Reason...

    Text Solution

    |

  20. Assertion. Xenon forms fluorides. Reason. Because 5d orbitals are av...

    Text Solution

    |