Home
Class 12
CHEMISTRY
Ag^(+)+hArr|Ag(NH(3))(2)|^(+), k(1) = 6....

`Ag^(+)+hArr|Ag(NH_(3))_(2)|^(+), k_(1) = 6.8 xx 10^(-3)`
`[Ag(NH_(3))]^(+) + NH_(3)hArr |Ag(NH_(3))_(2)|, k_(2) = 1.6xx10^(-3)`
Then the formation constant or `|Ag(NH_(3))_(2)|^(+)` is

A

`1.08xx10^(-7)`

B

`1.08xx10^(-5)`

C

`1.08xx10^(-9)`

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B

As the reaction takes placein two steps.
`beta=beta_(1)xxbeta_(2)=(6.8xx10^(-3))xx(1.6xx10^(-3))=10.8xx10^(-6)=1.08xx10^(-5)`
Promotional Banner

Topper's Solved these Questions

  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Fill in the blanks|29 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Conceptual Questions|51 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Advanced Problems|11 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    PRADEEP|Exercise IMPORTANT QUESTION FOR BOARD EXAMINATION|30 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos

Similar Questions

Explore conceptually related problems

If Ag^(+)+NH_(3)hArr[Ag(NH_(3))]^(+) , K_(1)=3.5xx10^(-3) and [Ag(NH_(3))]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+) , K_(2)=1.74xx10^(-3) . The formation constant of [Ag(NH_(3))_(2)]^(+) is :

Ag^(+) + NH_(3) ltimplies [Ag(NH_(3))]^(+), k_(1)=6.8 xx 10^(-5) [Ag(NH_(3))]^(+) + NH_(3) ltimplies [Ag(NH_(3))_(2)]^(+) , k_(2) = 1.6xx10^(-3) The formation constant of [Ag(NH_(3))_(2)]^(+) is :

Ag^(+)+NHP(3)hArr[Ag(NH_(3))]^(+), K_(1)=3.5=10^(-3) [Ag(NH)_(3)]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+),K_(2)=1.7xx10^(-3) then the formation constant of [Ag(NH_(3))_(2)]^(+) is

Zn^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(2)]^(+2), K_(1) = 2xx10^(-3) [Zn(NH_(3))_(2)]^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(4)]^(2+), K_(2) = 1.5xx10^(-3) Find out the instability constant?

{:(Ag^+ +NH_3 hArr[Ag(NH_3)]^+,,K_1=3.5xx10^-3),([Ag(NH_3)]^+ +NH_3 hArr[Ag(NH_3)_2]^+,,K_2=1.8xx10^-3):} then, the overall formation constant of [Ag(NH_3)_2]^+ is :

The hybridization of Ag in the linear complex [Ag(NH_(3))_(2)]^(+) is

PRADEEP-CORDINATION COMPOUNDS-Test Your Grip
  1. The primary and secondary valencies of chromium in the complex ion, di...

    Text Solution

    |

  2. The hybridisation of Fe in K(4)[Fe(CN)(6)] is

    Text Solution

    |

  3. Among the following ions which one has the highest paramagnetism?

    Text Solution

    |

  4. Which of the following is an outer orbital complex ?

    Text Solution

    |

  5. Which of the following compound has tetrahedral geometry?

    Text Solution

    |

  6. Which of the following statement is correct ? (CFSE = Crystal Field Sp...

    Text Solution

    |

  7. The increasing order of the crystal field splitting power of some comm...

    Text Solution

    |

  8. Which of the following configuration of ions has zero CFSE in both str...

    Text Solution

    |

  9. The most stable complex among the following is

    Text Solution

    |

  10. Ag^(+)+hArr|Ag(NH(3))(2)|^(+), k(1) = 6.8 xx 10^(-3) [Ag(NH(3))]^(+)...

    Text Solution

    |

  11. The dark blue colour of the solution formed when excess of ammonia is ...

    Text Solution

    |

  12. Prussian blue is obtained by mixing together aqueous solution of Fe^(3...

    Text Solution

    |

  13. The correct formula of Zeise's salt is

    Text Solution

    |

  14. Which of the following is a pi-acid ligand?

    Text Solution

    |

  15. The correct structure of Fe (CO)(5) is ?

    Text Solution

    |

  16. The oxidation state of nickel in [Ni(CO)(4)] is

    Text Solution

    |

  17. The non -existant metal carbonyl among the following is

    Text Solution

    |

  18. The metal-carbon bond in metal carbonyls prossesses :

    Text Solution

    |

  19. Which of the following is not considered as an organometallic compound...

    Text Solution

    |

  20. The coordination compound of which one of the following compositions w...

    Text Solution

    |