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Due to the presence of ambidenate ligand...

Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type `[Pd(C_(6)H_(5))_(2)(SCN)_(2)]` & `[Pd(C_(6)H_(5))_(2)(NCS)_(2)]` are

A

linkage isomers

B

coordination isomers

C

ionisation isomers

D

geometrical isomers

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The correct Answer is:
A
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Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] & [Pd(C_(6H_(5))_(2)(NCS)_(2)] are

Read the passage given below and answer the following questions : The existence of coordination compounds with the same formula but different arragements of the ligands was crucial in the development of coordination chemistry. Two or more compounds with the same formula but different arrangements of the atoms are called isomers. Isomers are compounds with the same molecular formula but different structural formulas and do not necessarily share similar properties. There are many different classes of isomers, like stereoisomers, enantiomers, and geometrical isomers. There are two main forms of isomerism: structural isomerism and stereoisomerism. The different chemical formulas in structural isomers are caused either by a difference in what ligands are bonded to the central atoms or how the individual ligands are bonded to the central atoms. The following questions are multiple choice questions. Choose the most appropriate answer: Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] are

[Pd(NH_(3))_(2)(SCN)_(2)] and [Pd(NH_(3))_(2)(NCS)_(2)] are :

Type of isomerism which exists between [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] is :

The following isomers refer to [{(C_(6)H_(5))_"(3)"P}_(2)Pd(SCN)_(2)] and [{(C_(6)H_(5))_(3)P}_(3)Pd(NCS)_(2)]

Type of isomerism which exists between [Pd( C_6H_5)_2 (SCN)_2] and [Pd(C_6H_5)_2(NCS)_2] is

PRADEEP-CORDINATION COMPOUNDS-MCQ
  1. Indicate the complex ion which shows geometrical isomerism :

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  2. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

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  3. Due to the presence of ambidenate ligands coordination compounds show ...

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  4. The two compounds [Co(SO(4))(NH(3))(5)]Br and [Co(SO(4))(NH(3))(5)]Cl ...

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  5. A chelating agent has two or more than two donor atoms to bind to a si...

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  6. Which of the following species is not expected to be a ligand?

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  7. What kind of isomerism exists between [Cr(H(2)O)(6)]Cl(3) (violet) and...

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  8. IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is

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  9. Atomic number of Mn. Fe and Co are 25, 26 and 27 respectively. Which o...

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  10. Atomic number of Mn, Fe, Co and Ni are 25, 26, 27 and 28 respectively....

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  11. Which of the following options are correct for [Fe(CN)(6)]^(3-) comple...

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  12. An aqueous pink solution of cobalt (II) chloride changes to deep blue ...

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  13. Which of the following complexes are homoleptic ?

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  14. Which of the following complexes are heteroleptic ?

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  15. Identify the optically active compounds from the following :

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  16. Identify the correct statements for the behaviour of ethane-1, 2-diami...

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  17. Which of the following complexes show linkage isomerism ?

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  18. 2 : 4 Dinitrophenyl hydrazine is an example for

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  19. The correct structure of ethylenediamineteraacetic acid (EDTA) is .

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  20. In Tollen's reagent, the oxidation number, coordination number and eff...

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