On the basis of crystal field theory explain why Co(III) Forms paramagnetic octahedral complex with weak field ligands whereas it forms diamagnetic octahedral complex with strong field ligands.

Explanation

With weak field ligands, `Delta_(0)ltP`. Electronic configuration of Co(III) will be `t_(2g)^(4)e_(g)^(2)`. Thus, it has 4 unpaired electrons and is paramagnetic. With strong field ligands, `Delta_(0)gtP`. Electronic configuration will be `t_(2g)^(6)e_(g)^(0)` has no unpaired electron and is diamagnetic.