Home
Class 12
CHEMISTRY
Why do compounds having similar geometry...

Why do compounds having similar geometry have different magnetic moment ?

Text Solution

Verified by Experts

The difference is due to presence of weak and strong ligands. If ligand is strong (high CFSE), electrons in d-subshell will pair up and magnetic moment will be low. If ligand is weak (low CFSE), electrons will not pair up. Hence, magnetic moment will be high, e.g. `[CoF_(6)]^(3-) and [Co(NH_(3))_(6)]` both are octahedral but former is paramagnetic while latter is diamagnetic.
Promotional Banner

Topper's Solved these Questions

  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Matching Type Question|5 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Assertion And Reason Types Question|5 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise MCQ|190 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    PRADEEP|Exercise IMPORTANT QUESTION FOR BOARD EXAMINATION|30 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos

Similar Questions

Explore conceptually related problems

The pair of compounds having similar geometry are :

The pair having similar geometry is

The pair having similar geometry is :

The compound having tetrahedral geometry is

The compound having a tetrahedral geometry is .

Which hass //have magnetic moment ?

PRADEEP-CORDINATION COMPOUNDS-Short Answer Questions
  1. Explain why [Fe(H(2)O)(6)]^(3+) has magnetic moment value of 5.92 BM w...

    Text Solution

    |

  2. Arrange following complex ions in increasing order of crystal field sp...

    Text Solution

    |

  3. Why do compounds having similar geometry have different magnetic momen...

    Text Solution

    |

  4. CuSO(4).5H(2)O is blue in colour while CuSO(4) is colourless. Why ?

    Text Solution

    |

  5. Name the type of isomerism when ambidentate ligands are attched to cen...

    Text Solution

    |

  6. Double Salt and Coordination Compound

    Text Solution

    |

  7. Explain with examples the following : (i) coordination number (ii) o...

    Text Solution

    |

  8. What is meant by unidentate, bidentate and ambidentate ligands ? Illus...

    Text Solution

    |

  9. Determine the oxidation states of central metal ions in the following ...

    Text Solution

    |

  10. Write IUPAC name of the following coordination compounds : (a) (i) [...

    Text Solution

    |

  11. (a) Write the IUPAC of the isomer of the following complex : [Pt(NH(...

    Text Solution

    |

  12. (a) Write the IUPAC name of the isomer of the following complex : [C...

    Text Solution

    |

  13. (a) Write the IUPAC name of the following complex : [Co(NH(3))(4)Cl(...

    Text Solution

    |

  14. What are chelates ? Giving one example write the importance of chelate...

    Text Solution

    |

  15. List various types of isomerism possible for coordination compounds, g...

    Text Solution

    |

  16. Define cis and trans isomerism. Draw the cis and trans isomers of [Co(...

    Text Solution

    |

  17. Draw all the possible isomers (structural and stereoisomeric) having t...

    Text Solution

    |

  18. The aqueous solution of a complex compound having the formula coBrCl(2...

    Text Solution

    |

  19. [Ni(CO)(4)] possess tetrahedral geometry while [Pt(NH(3))(2)Cl(2)] has...

    Text Solution

    |

  20. Using the valence bond theory, predict the geometry and magnetic chara...

    Text Solution

    |