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Determine the oxidation states of centra...

Determine the oxidation states of central metal ions in the following complex compounds :
(i) (a) `K_(4)[Fe(CN)_(6)]` (b) `[Co(NH_(3))_(6)]Cl_(3)`
(ii) (a) `K_(3)[Fe(CN)_(6)]` (b) `[PtCl_(4)]^(2-)` (c ) `[CoBr_(2)(CN)_(2)]^(+)`
(iii) (a) `[Pt(NH_(3))_(3)Cl_(3)]` ion (b) `Na_(4)[Ni(CN)_(4)]` (c ) `[Zn(H_(2)O)_(3)OH]^(+)`

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AI Generated Solution

To determine the oxidation states of the central metal ions in the given complex compounds, we will follow a systematic approach. Below is the step-by-step solution for each part of the question. ### (i) #### (a) `K_(4)[Fe(CN)_(6)]` 1. Identify the oxidation state of potassium (K). Potassium is an alkali metal and has an oxidation state of +1. 2. The cyanide ion (CN) is a ligand with an oxidation state of -1. 3. The overall charge of the complex ion `[Fe(CN)_(6)]` is neutral (0). 4. Set up the equation: ...
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Give the oxidation states of the central matal in the following complex compounds , (i) K_(3)[Fe(CN)_(6)] (ii) [PtCl_(4)]^(2-) (iii) [Co(en)_(2)Cl_(2)]^(+) .

Write the IUPAC names of : (a) K_(4)[Fe(CN)_(6)] (b) [Co(NH_(3))_(6)]Cl_(3) (c) Na[AIF_(6)]

Which of the following is more stable ? (1) K_(4)[Fe(CN)_(6)] or K_(3)[Fe(CN)_(6)] (2) [Co(NH_(3))_(6)]^(3+) or [Co(en)_(2)(NH_(3))_(2)]^(3+) (3) [NiCl_(4)]^(2-) or [Ni(CN)_(4)]^(2-)

Write the IUPAC names of the following coordiantion compounds: (i) [Co(NH_(3))_(6)]Cl_(3) (ii) [Co(NH_(3))_(5)Cl]Cl_(2) (iii) K_(3)[Fe(CN)_(6)] (iv) K_(3)[Fe(C_(2)O_(4))_(3)] (v) K_(2)[Pd Cl_(4)] (vi) [Pt(NH_(3))_(2)Cl(NH_(2)CH_(3))]Cl

The hybridization states of the central atom in the complexes [Fe(CN)_(6)]^(3-),[Fe(CN)_(6)]^(4-) and [Co(NO_(2))_(6)]^(3-) are:

Calculate the oxidation state of central metal atom in i) [Co(NH_(3))_(5)Cl]^(2+) ii) K_(4)[Fe(CN)_(6)] iii) [Co(NO_(2))_(2)(py)_(2)(NH_(3))_(2)]NO_(3)

PRADEEP-CORDINATION COMPOUNDS-Short Answer Questions
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  7. (a) Write the IUPAC name of the following complex : [Co(NH(3))(4)Cl(...

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  10. Define cis and trans isomerism. Draw the cis and trans isomers of [Co(...

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  14. Using the valence bond theory, predict the geometry and magnetic chara...

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  15. Consider the coordination compound, [Co(NH(3))(5)SO(4)]Br (i) Write ...

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  16. Using the valence bond approach, deduce the shape and magnetic charact...

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  17. On the basis of valence bond theory, account for the hybridisation, sh...

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  18. Write the name, stereochemistry and magnetic behaviour of the followin...

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  19. Give an example of each of the following : (i) Outer orbital octahed...

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  20. Compare the magnetic behaviour of the complex entities [Fe(CN)(6)]^(4-...

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