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Pick out the correct statement with respect to `[Mn(CN)_(6)]^(3-)`:

A

It is `sp^(3)d^(2)`-hybridized and octahedral

B

It is `sp^(3)d^(2)`-hybridized and tetrahedral

C

It is `d^(2)sp^(3)`-hybridized and octahedral

D

It is `dsp^(2)`-hybridized and square planar

Text Solution

Verified by Experts

The correct Answer is:
C

In `[Mn(CN)_(6)]^(3-), Mn^(3+)=3d^(4)`

In presence of strong field ligand, `CN^(-)`,
`[Mn(CN)_(6)]^(3-)` =
ltbgt Thus, the complex is `d^(2)sp^(3)` hybridized having octahedral shape.
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  3. Pick out the correct statement with respect to [Mn(CN)(6)]^(3-):

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  4. Which of the following complexes exhibits the highest paramagnetic beh...

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  7. Hybridization shape and magnetic moment of K(3)[Co(CO)(6)] is

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  8. Which one of the following is an outer orbital complex and exhibits pa...

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  10. The spin only magnetic moment value of Cr(CO)(6) is

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  11. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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  12. Which one of the following is wrongly matched ?

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  13. Geometrical shapes of the complex formed by the reaction of Ni^(2+) wi...

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  14. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

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  15. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

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  16. Which of these statements about [Co(CN)6]^(3-) is true?

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  19. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  20. Which of the following is diamagnetic in nature ?

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