Home
Class 12
CHEMISTRY
Geometrical shapes of the complex formed...

Geometrical shapes of the complex formed by the reaction of `Ni^(2+)` with `Cl^(Θ),CN^(Θ)` and `H_(2)O` are :

A

Octahedral, tetrahedral and square planar

B

Tetrahedral, square planar and octahedral

C

Square planar, tetrahedral and octahedral

D

Octahedral, square planar and octahedral

Text Solution

Verified by Experts

The correct Answer is:
B

`Ni^(2)+4Cl^(-)rarr[Ni(Cl)_(4)]^(2-)`, tetrahedral, `sp^(3)`, hybridization
`Ni^(2+)+4CN^(-)rarr[Ni(CN)_(4)]^(2-)`, square planar, `dsp^(2)` hybridization
`Ni^(2)+6H_(2)Orarr[Ni(H_(2)O)_(6)]^(2+)`, octahedral, `sp^(3)d^(2)` hybridization.
Promotional Banner

Topper's Solved these Questions

  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Short Answer Questions|64 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Matching Type Question|5 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise NCERT Exercises|32 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    PRADEEP|Exercise IMPORTANT QUESTION FOR BOARD EXAMINATION|30 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos

Similar Questions

Explore conceptually related problems

Geometrical shapes of the complews formed by the reaction of Ni^(2+) with CI^(Θ),CN^(Θ) and H_(2)O respectively ,are .

Geometrical shapes of the complexes fromed by the reaction of Ni^(2+) with CN^- and H_2O , respecitively , are :

The IUPAC name of the complex Ni[C_(4)H_(7)O_(2)N_(2)] formed by the reaction between Ni^(2+) and dimethylglyoxime is

Calculate the entropy of overset(Θ)OH ion at 298K . Given: a. H_(2)O hArr H^(o+) + overset(Θ)OH (DeltaH = 13.4 kcal) b. K_(eq) for the reaction = 10^(-14) . c. S^(Θ) (H^(o+)) = 0.0 d. S^(Θ) (H_(2)O) = 16.7 cal//mol k .

How many geometrical isomers are there fore (a) [Co(NH_(3))_(2)CI_(4)]^(Θ) (b) [AuCI_(2)Br_(2)]^(Θ) (square planar) (c ) [CuCI_(2)Br_(2)]^(2-) (tetrahedral) .

PRADEEP-CORDINATION COMPOUNDS-MCQ
  1. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

    Text Solution

    |

  2. Which one of the following is wrongly matched ?

    Text Solution

    |

  3. Geometrical shapes of the complex formed by the reaction of Ni^(2+) wi...

    Text Solution

    |

  4. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

    Text Solution

    |

  5. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

    Text Solution

    |

  6. Which of these statements about [Co(CN)6]^(3-) is true?

    Text Solution

    |

  7. Which of the following complex has minimum magnitude of Delta^(0) ?

    Text Solution

    |

  8. Crystal field stabilization energy for high spin d^4 octahedral comple...

    Text Solution

    |

  9. Low spin complex of d^6-cation in an octahedral field will have the fo...

    Text Solution

    |

  10. Which of the following is diamagnetic in nature ?

    Text Solution

    |

  11. In Spectrochemical series , chorine is above than water . I .e ...

    Text Solution

    |

  12. The magnitude of crystal field stabilisation energy (CFSE of Delta(1))...

    Text Solution

    |

  13. Which of the following complexions is expected to absorb visible light...

    Text Solution

    |

  14. Correct increasing order for the wavelength of absorption in the visib...

    Text Solution

    |

  15. Which of the following compounds is not yellow coloured ?

    Text Solution

    |

  16. Which of the following is high spin complex ?

    Text Solution

    |

  17. Which one of the following ligand is capable of forming a low spin as ...

    Text Solution

    |

  18. Which of the following shell from an octahedral complex

    Text Solution

    |

  19. [NiCl(2){P(C(2)H(5))(2)(C(6)H(5))}(2)] exhibits temperature dependent ...

    Text Solution

    |

  20. Coordination number of Cr is three. A comlex ion of Cr with C(2)O(4)^(...

    Text Solution

    |