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Which of these statements about [Co(CN)6...

Which of these statements about `[Co(CN)_6]^(3-)` is true?

A

`[Co(CN)_(6)]^(3-)` has four unpaired electrons and will be in a high-spin configuration

B

`[Co(CN)_(6)]^(3-)` has no unpaired electrons and will be in a high-spin configuration

C

`[Co(CN)_(6)]^(3-)` has no unpaired electrons and will be in a low-spin configuration

D

`[Co(CN)_(6)]^(3-)` has four unpaired electrons and will be in a low-spin configuration

Text Solution

Verified by Experts

The correct Answer is:
C

`[Co(CN)_(6)]^(3-)` has cobalt in +3 oxidation state

As `CN^(-)` is a strong field ligand, all electrons will be paired up and complex will be a low-spin complex.
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PRADEEP-CORDINATION COMPOUNDS-MCQ
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  2. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

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  3. Which of these statements about [Co(CN)6]^(3-) is true?

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  4. Which of the following complex has minimum magnitude of Delta^(0) ?

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  6. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  7. Which of the following is diamagnetic in nature ?

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  9. The magnitude of crystal field stabilisation energy (CFSE of Delta(1))...

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  12. Which of the following compounds is not yellow coloured ?

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  18. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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